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Nitridation of polycrystalline titanium as studied by in situ angle-resolved x-ray photoelectron spectroscopy (1988)

Ermolieff, A. ; Bernard, P. ; Marthon, S. ; [et al.]

Chichester [u.a.] : Wiley-Blackwell

Surface and Interface Analysis 11 (1988), S. 563-568

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ISSN: 0142-2421

Keywords: Chemistry ; Polymer and Materials Science

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Physics

Notes: Nitridation of polycrystalline titanium was investigated in situ at about 550°C by angle-resolved x-ray photoelectron spectroscopy (XPS). The nitrogen pressure was varied from 10-4mbar to 1 mbar. The distribution of nitrogen in the titanium and the chemical bonding present were deduced from XPS measurements. Titanium nitridation passes through several stages as a function of the nitrogen exposure. The nitrogen concentration varies linearly with the logarithm of pressure and dose. Using the modified Ritchie-Hund theory it was shown that the kinetics of titanium nitridation follows a cubic law.

Additional Material: 10 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/sia.740111105

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