ISSN:
1612-1112
Keywords:
Gas chromatography
;
Stationary liquid, choice of
;
Physico-chemical data
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Summary A table of data for acidity, basicity, polarity and London potential for stationary phases is given. These provide guidance in choosing a stationary phase for a given task from the 26 substances listed. The indices are calculated from infra-red shifts of 1-chlorobutane and the visible wavelength shifts of l2 when they are dissolved in the stationary phases, from NMR estimates of acidity and basicity and from relative retention data. They replace the less reliable data of Burns and Hawkes. Methods of determining the indices are suggested that require only a gas chromatograph and can be applied by technicians with no specialized understanding of solution parameters. An attempt to add electron donoracceptor indices to the table was unsuccessful. A further table is given of the slopes of the log plots d(logt′)/dC for use in extrapolating from one homologue to another on these stationary phases.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF02310386
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