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  • 1
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The crystal structure of the complex [phen · phen · phen] · NaBr · 2 CHCl3 of the macrobicyclic ligand 1 has been determined. The complex is of cryptate type, the Na+ cation being contained in the molecular cavity of 1 and coordinated to all eight N-atoms. The ligand has a propeller shape and interconverts in solution between the two enantiomeric helical forms.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: An X-ray diffraction analysis of the crystalline complex 2b (MLn — TiCl4) shows a chelation of the carbonyl O-atom and the upper SO2 O-atom by TiCl4, a slightly pyramidal N-atom, and a π -face-stereoselective shielding of the C(α)-Si face by the CH2(3) group. The Ti-atom is in a pseudo-octahedral environment.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 68 (1985), S. 975-980 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: 1H-Cyclopropa[b]naphthalene (10a) and 3-methyl or dimethyl derivatives have been synthesized by interception of appropriately substituted o-quinodimethanes 3 with 1-bromo-2-chlorocyclopropene 5, and subsequent dehydrohalogenation of the adducts. The o-quinodimethane derivatives 3 in turn were obtained from the diynes 7 via base-induced isomerization to bisallenes 8 and thermal electrocyclic ring closure.
    Additional Material: 1 Tab.
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  • 4
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The stereochemistry of the Diels-Alder reaction of 1,2-dichloro-3,3-difluorocyclopropene (5a) to 1,4-diphenyl-1,3-butadiene (6) and 1,3-diphenylisobenzofuran (7) was unambiguously established by X-ray structure determination. In all cases known so far, tetrahalogenocyclopropenes add exo to open-chain dienes and furans. The previously reported exo-addition product (2a) of l-bromo-2-chlorocyclopropene (5b) to 7 allows assignments of the stereochemistry of other additions of 5b to furans. exo-Addition usually predominates, but in some cases endo- adducts are also formed. This contrasts with reports in the literature that 5b adds preferentially endo to open-chain dienes.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Helvetica Chimica Acta 69 (1986), S. 1546-1553 
    ISSN: 0018-019X
    Keywords: Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A series of 3,4-disubstituted (4a, b) or 3,4-fused (4c-e) 1,1-di-fluorocyclopropabenzenes, including the very strained 1,1-difluoro-3,4-dihydro-1 H-cyclobuta[a]cyclopropa[d]benzene (4e) have been synthesized and characterized. Dissolution of these difluoro derivatives in fluorosulfonic acid affords the fluoro cations 3a-e. 1H-, 19F-, and 13C-NMR data of the cations are reported and discussed with respect to those of the precursors.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Applied Organometallic Chemistry 1 (1987), S. 535-540 
    ISSN: 0268-2605
    Keywords: Bromoquinolines ; Coupling reaction ; Biquinolines ; Tris(triphenylphosphine)nickel(0) ; Pyridine-nickel complex ; Chemistry ; Organic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Tris(triphenylphosphine)nickel(0) (A) and a zerovalent pyridine-nickel complex (B) have been used as reagents for the coupling reaction of 3-, 6- and 8-bromoquinolines: 3,3′-, 6-6′- and 8,8′- Biquinolines were obtained in quantitative yields when A was used as the coupling reagent. B gave always a mixture of the n,n′ -biquinoline and substitution products. A mechanism can be outlined to explain the coupling reaction of bromoquinolines using zerovalent nickel complexes.
    Additional Material: 4 Tab.
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  • 7
    Publication Date: 2011-08-19
    Description: The recursive difference equations of Kalman filtering and Bryson-Frazier fixed time-interval smoothing, arising in the state estimation theory for linear state space systems, are used here to solve problems of serial manipulator inverse and forward dynamics. The configuration analyzed is that of a joint connected N-link serial manipulator attached to an immobile base. The equivalence between the filtering and smoothing techniques from state estimation theory and recursive robot dynamics methods is demonstrated. Several areas for future research are suggested.
    Keywords: CYBERNETICS
    Type: IEEE Journal of Robotics and Automation (ISSN 0882-4967); RA-3; 624-639
    Format: text
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  • 8
    Publication Date: 2011-08-19
    Description: Recursive forward dynamics algorithms are developed and presented for an arbitrary number of robot arms moving a commonly held object. The multiarm forward dynamics problem is to find the angular accelerations at the joints and the contact forces that the arms impart to the task object. The problem also involves finding the acceleration of this object. The multiarm forward dynamics solutions provide a thorough physical and mathematical understanding of the way several arms behave in response to a set of applied joint moments. Such an understanding simplifies and guides the subsequent control design and experimentation process. The forward dynamics algorithms also provide the necessary analytical foundation for conducting analysis and simulation studies. The multiarm algorithms are based on the filtering and smoothing approach recently advanced for single-arm dynamics, and they can be built up modularly from the single-arm algorithms. The algorithms compute recursively the joint angle accelerations, the contact forces, and the task-object accelerations. Algorithms are also developed to evaluate in closed form the linear transformations from the active joint moments to the joint angle accelerations, to the task object accelerations, and to the task-object contact forces. A possible computing architecture is presented as a precursor to a more complete investigation of the computational performance of the dynamics algorithms.
    Keywords: CYBERNETICS
    Type: IEEE Transactions on Robotics and Automation (ISSN 1042-296X); 5; 510-521
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  • 9
    Publication Date: 2011-08-19
    Description: This paper advances an approach to the determination of shape of static distributed systems. It also illustrates the application of the approach to the problems of surface diagnosis of large parabolic reflectors. The estimation methods developed combine in an optimal sense the information from an elliptic model of the structure and from measurements of the structural deflection and of the far-field pattern changes due to the structural deformation. The estimators have a predictor-corrector structure, quite similar to that of a Kalman filter. The system model is first used to obtain a predicted estimate. A correction term is then added to the prediction to obtain the final state estimate. The relative weighting between prediction and correction terms is determined by an estimator gain. As in a Kalman filter, the estimator gain can be expressed in terms of the state estimation error covariance.
    Keywords: CYBERNETICS
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  • 10
    Publication Date: 2013-08-29
    Description: A new test technology is described which was developed for space system integration. The ultimate purpose of the system is to support the automatic generation of test systems in real time, distributed computing environments. The Intelligent Test Integration System (ITIS) is a knowledge based layer above the traditional test system components which can generate complex test configurations from the specification of test scenarios.
    Keywords: CYBERNETICS
    Type: NASA, Marshall Space Flight Center, Second Conference on Artificial Intelligence for Space Applications; p 177-185
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