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  • Analytical Chemistry and Spectroscopy  (4)
  • Noctuidae  (2)
  • 1985-1989  (6)
  • 1
    ISSN: 1573-1561
    Keywords: Sex pheromone ; Lepidoptera ; Noctuidae ; Pseudoplusia includens ; Trichoplusia ni ; multicomponent pheromone blends ; sustained-flight tunnel ; behavioral thresholds
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract The response of male cabbage looper (CL) and soybean iooper (SBL) moths was observed in the flight tunnel and measured in field tests to the six-component CL pheromone, the five-component SBL pheromone, and toZ7–12: OAc, the major component common to each pheromone. In both the flight tunnel and the field, male CL exhibited significantly greater levels of response to their six-component blend than toZ7–12: OAc alone. A low level of cross-attraction of male CL to the SBL pheromone was observed in both the flight tunnel and the field, but it was quantitatively and qualitatively similar to their response toZ7–12: OAc alone. Thus the minor components of the SBL blend did not appear to disrupt the flight behavior of male CL. With respect to SBL, in the flight tunnel males also exhibited a greater level of response to the five-component blend compared toZ7–12: OAc, but in the field their response was not significantly different to either treatment. There was also a low level of cross-attraction of male SBL to the CL blend, but this appeared to involve a significant arrestment effect on the upwind flight of males, as well as a difference in male sensitivity to the blend of components compared withZ7–12: OAc alone. The observed arrestment effect may have been due to male perception of one or more minor components of the CL pheromone. The results show that the multicomponent pheromones of these species function effectively as specific mating signals and that discrimination of odor quality by male moths can occur as the result of minor components affecting male sensitivity or their upwind flight response to the pheromone.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    Journal of chemical ecology 13 (1987), S. 1351-1360 
    ISSN: 1573-1561
    Keywords: Sex pheromone ; Lepidoptera ; Noctuidae ; Pseudoplusia includens ; sustained-flight tunnel ; (Z)-7-dodecenyl acetate ; dodecyl acetate ; 11-dodecenyl acetate ; (Z)-7-dodecenyl propionate ; (Z)-7-dodecenyl butanoate
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology , Chemistry and Pharmacology
    Notes: Abstract Analysis of sex pheromone glands from individual female soybean looper moths showed that in addition to the previously identified main component (Z)-7-dodecenyl acetate, the compounds dodecyl acetate, 11-dodecenyl acetate, (Z)-7-dodecenyl propionate, and (Z)-7-dodecenyl butanoate were also produced. Two of the components, 12∶OAc and 11–12∶OAc, were not detected in a single analysis of female effluvium. Flight-tunnel tests showed that the five-component and three-component blends were equal to each other and to a female extract (〉 80% source contacts) and that the mixtures were superior toZ7–12∶OAc alone. Field tests indicated that the five-component blend was significantly more attractive thanZ7–12∶OAc alone at a dosage of 1 mg, but that the blend was only slightly better at 3 mg.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Orthoquinone diazides, which are widely used in microlithography, have attracted considerable attention, especially in terms of their application in the production of high-contrast resists. Previous electron impact mass spectrometric results have confirmed that the primary fragmentation process of these compounds is the elimination of N2 to form an indenoketene ion. This is analogous to the photodecomposition pathway which makes them effective in the lithographic process. Those results also revealed the occurrence of an alternative process, which involves a two-hydrogen reduction of the intermediate species formed prior to conversion to the ketene. The present study investigates the behaviour of the orthoquinone diazides when there is an abundance of protons available to form the reduction product. Several different types of diazonaphthalenone sulfonyl esters, ranging in complexity from the monosubstituted phenol esters to disubstituted dihydroxybenzophenones, were examined using fast atom bombardment mass spectrometry. Although reduction was the primary process in the hydrogen-rich matrices, the extent of reduction was characteristic of the particular isomer as well as the matrix used.
    Additional Material: 7 Ill.
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  • 4
    ISSN: 0749-1581
    Keywords: Adsorption NMR ; Charcoal ; Alcohols ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A 1H NMR study of methyl, ethyl, n-propyl, isopropyl and allyl alcohols adsorbed on charcoals with various pore structures showed that the adsorption mechanism is by capillary condensation in pores with radii smaller than 30 Å, and by mono-/multi-layer adsorption on the solid surface of pores with larger radii. This mechanism is identical with that of adsorbed hydrocarbons. The 13C NMR parameters suggest that the adsorbed alcohols are preferentially oriented in the monolayer, with the methyl groups bonded to the solid surface. Longer chain alcohols are bent in capillaries with radii smaller than 10 Å. The broadening of the 13C resonances was partly eliminated in magic angle spinning experiments by using a spinning rate of 1.5-1.8 kHz.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 27 (1989), S. 57-60 
    ISSN: 0749-1581
    Keywords: 1H NMR ; Propylene oxide-water ; Nature of hydrogen bond ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: As an electron donor solvent, propylene oxide (PO) forms a hydrogen bond with water in their binary mixture. The repulsion produced by the electrostatic field from the PO…HOH hydrogen bond forces the protons and methyl group of PO to bend away from the —O— group and results in the approach of these protons into the plane of the three-membered ring. Consequently, they experience a stronger paramagnetic field from the ring current and their 1H resonances shift to a lower field. The changes of the H—C—H angle and H—C—C—H dihedral angles of PO in water cause the geminal coupling constant and the vicinal cis coupling constant to decrease and the vicinal trans coupling constant to increase.
    Additional Material: 2 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 25 (1987), S. 575-578 
    ISSN: 0749-1581
    Keywords: Acetone-water ; Multinuclear NMR ; Protonation ; Water structure ; 1H NMR of water ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The protonation of acetone in water for a wide range of compositions of the binary mixture was studied by multinuclear NMR spectroscopy. Formation constants (K1 and K2) and 13C, 17O and 1H chemical shifts of the 1:1 and 1:2 complexes were evaluated. The correlation of the 1H chemical shift of uncombined water with its concentration, Δ0H2O = A + B In [H2O]eq, recently derived for the trimethyl phosphate-water system, was verified. A measure of the fraction of monomer species existing in the uncombined water at each composition was obtained. The results are discussed with respect to the structure of water.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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