ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

X
feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Physical Chemistry  (4)
  • *Convection
  • Chemistry and Materials (General)
  • 1985-1989  (4)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    A kinetics study of the reaction of Cl with NO2This work was supported by a NASA contract. The results were presented at the 13th Informal Conference on Photochemistry, Clear Water Beach, Florida, January 4-7, 1978. (1988)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 20 (1988), S. 811-814 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The third order rate coefficients for the addition reaction of Cl with NO2, Cl + NO2 + M → ClNO2 (ClONO) + M; k1, were measured to be k1(He) = (7.5 ± 1.1) × 10-31 cm6 molecule-2 s-1 and k1(N2) = (16.6 ± 3.0) × 10-31 cm6 molecule-2 s-1 at 298 K using the flash photolysis-resonance fluorescence method. The pressure range of the study was 15 to 500 torr He and 19 to 200 torr N2. The temperature dependence of the third order rate coefficients were also measured between 240 and 350 K. The 298 K results are compared with those from previous low pressure studies.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550201005
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 2
    Electronic Resource
    Electronic Resource
    Tables of rate constants extracted from chemical kinetics and photochemical data for use in stratospheric modeling. Evaluation number 7 (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1135-1151 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: These tables of evaluated rate constants for use in stratospheric modeling have been taken from the most recent report of the NASA Panel that has been periodically producing such reviews. They are reproduced here to make a broader community aware of their existence. This article should NOT be cited, nor should these rate constants be used without consulting the full report. All citations should be to that original report (JPL Publ. 85-37), which contains extensive documentation and discussion of the rationale of the evaluation. Copies may be obtained by requesting JPL Publ. 85-37 from Documentation Services, 111-116B, Jet Propulsion Laboratory, 4800 Oak Grove Drive, Pasadena, CA 91109.
    Additional Material: 2 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550171010
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 3
    Electronic Resource
    Electronic Resource
    Kinetic study of the reaction of OH with HCl from 240-1055 K (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 1281-1297 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Absolute rate coefficients for the reaction of OH with HCl (k1) have been measured as a function of temperature over the range 240-1055 K. OH was produced by flash photolysis of H2O at λ 〉 165 nm, 266 nm laser photolysis of O3/H2O mixtures, or 266 nm laser photolysis of H2O2. OH was monitored by time-resolved resonance fluorescenceor pulsed laser-induced fluorescence. In many experiments the HCl concentration was measured in situ in the slow flow reactor by UV photometry. Over the temperature range 240-363 K the following Arrhenius expression is an adequate representation of the data: k1 = (2.4 ± 0.2) × 10-12 exp[-(327 ± 28)/T]cm3 molecule-1 s-1. Over the wider temperature range 240-1055 K, the temperature dependence of k1 deviates from the Arrhenius form, but is adequately described by the expression k1 = 4.5 × 10-17 T1.65 exp(112/T) cm3 molecule-1 s-1. The error in a calculated rate coefficient at any temperature is 20%.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550171206
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
  • 4
    Electronic Resource
    Electronic Resource
    Kinetics of the reactions of hydroxyl radical with aliphatic aldehydes (1985)
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 17 (1985), S. 303-313 
    Details
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Rate coefficients for OH reactions with the 2-5 carbon aliphatic aldehydes have been measured under pseudo first-order conditions in OH. OH was generated by flash photolysis of H2O at wavelengths greater than 165 nm and its concentration monitored using time-resolved resonance fluorescence spectroscopy. Two reactions were studied only at 298 K while five reactions were studied over the temperature range 250-425 K; negative activation energies were observed for all five reactions. Aldehyde reactivity toward OH is nearly independent of the identity of the hydrocarbon side chain. Our results are compared with those obtained in previous studies of OH-aldehyde reaction kinetics and their mechanistic implications are discussed.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/kin.550170307
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
    Paper (German National Licenses)
    Fulltext
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...