ISSN:
0009-2940
Keywords:
(Cyclopentadienyl)manganese complexes
;
(Cyclopentadienyl)rhodium complexes
;
Perhalogenocyclopentadienyl complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Description / Table of Contents:
Chemistry of Complexes of Perhalogenated Cyclopentadienes and Alkynes. IV. - Preparation, Reactions, and Structures of Alkylthio- and Phenylthio-Substituted (Cyclopentadienyl)manganese and -rhodium ComplexesThe syntheses and crystal structures of (C5Cl4SPh)Rh(1,5-COD) (2b), [C5Cl3(SR)2Mn](CO)3 [R = Ph (4a), Me (4b)] and [C5Cl2-(SPh)3]Mn(CO)3(5a) as well as the syntheses of [C5Cl5-x- (SBu)x]Mn(CO)3 [x = 1 (3b), 2 (4c), 3 (5b)] and the reactions of [C5Cl2(SR)3]Mn(CO)3 and [C5(SMe)5]Mn(CO)3 with PdCl2(Ph-CN)2 are described. The cyclopentadienyl ring in 2b is not planar, and the three phenyl rings of 5a are parallel to each other.
Notes:
Die Darstellung und die Kristallstrukturen von (C5Cl4SPh)Rh-(1,5-COD)(2b), [C5Cl3(SR)2Mn](CO)3 [R = Ph (4a), Me (4b)] und [C5Cl2(SPh)3]Mn(CO)3 (5a) sowie die Darstellung von [C5Cl5-x (SBu)x]Mn(CO)3 [x = 1 (3b), 2 (4c), 3 (5b)], ferner Reaktionen von [C5Cl2(SR)3]Mn(CO)3 und [C5(SMe)5]Mn(CO)3 mit PdCl2-(PhCN)2 werden beschrieben. In 2b ist der Cyclopentadienylring nicht planar, und in 5a stehen die drei Phenylringe nahezu parallel.
Additional Material:
5 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19891220404
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