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  • Polymer and Materials Science  (4)
  • Food Science, Agricultural, Medicinal and Pharmaceutical Chemistry  (1)
  • Wiley-Blackwell  (5)
  • Springer Nature
  • 1985-1989  (5)
Collection
Publisher
  • Wiley-Blackwell  (5)
  • Springer Nature
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 190 (1989), S. 2279-2286 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Chitosan films were prepared by casting from solutions in dilute acetic acid containing methanol, acetone, or dimethyl sulfoxide. Induced changes in the structural orientation of the molecules within the film were studied by wide angle X-ray diffraction, and it was shown that the presence of a high concentration of organic solvent in solution altered the crystal structure of the resultant films, rendering them insoluble in water. Benzoylated and butyrylated derivatives of chitin and chitosan were prepared and characterised by infrared spectroscopy. Films of these derivatives were prepared by casting from a number of organic solvents and water, and the structures examined in more detail by wide angle X-ray diffraction. The introduction of the aliphatic and aromatic groups to the polysaccharide backbone was thus shown to disrupt the natural orientation of the polymer chains; the solubility of the acylated derivatives is discussed with respect to these structural changes.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 641-656 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Chitosan has been prepared from prawn shell and crab shell chitin. The molecular weight of the material derived from prawn shells is higher than that obtained from crab shell. The molecular weight, tensile strength, elongation at the break, and hydrophilic properties of chitosan are extremely dependent on the degree of deacetylation achieved when chitin is hydrolyzed to chitosan. Graft copolymers have been prepared with chitosan and a series of vinyl monomers using both heterogeneous and homogeneous reaction conditions. The hydrophilic properties of chitosan can be modified by blending with poly(vinyl alcohol).
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1249-1257 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A mass transport model has been developed to predict theoretical breakthrough curves in fixed bed adsorbers. The model has been tested using experimental data obtained for the adsorption of Acid Blue 25 on chitin. The effective diffusivity can be determined for the adsorption process by best fitting experimental and theoretical breakthrough curves and was found to be 5.5 × 10-6 cm2 s-1.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 4325-4335 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The kinetics of the adsorption of various dyestuffs onto chitin have been studied. The dyestuffs used are Neoland Blue 2G, Eriochrome Flavine A, and Solophenyl Brown 3RL and a number of process variables were considered, such as adsorbent mass and dye concentration. The mass transfer model is based on the assumption of a pseudoirreversible isotherm and two resistances to mass transfer. These are external mass transfer and internal pore diffusion mass transfer. The rate of adsorption of dyestuffs onto chitin can thus be described by an external mass transfer coefficient and a pore diffusion coefficient. The external mass transfer coefficients are 5.0 × 10-5, 5.0 × 10-5, and 1.0 × 10-5 m·s-1 and the pore diffusivities are 3.0 × 10-10 and 4.0 × 10-11 m2·s-1 for Neolan Blue 2G, Eriochrome Flavine A, and Solophenyl Brown 3RL, respectively.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Archives of Insect Biochemistry and Physiology 12 (1989), S. 231-252 
    ISSN: 0739-4462
    Keywords: sterols ; acylglycerides ; glycerol ; hemolymph ; corn earworm ; Chemistry ; Food Science, Agricultural, Medicinal and Pharmaceutical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology
    Notes: Two vertebrate hypolipidemic agents, cholestyramine and niacin, affected the growth and development of Heliothis zea as well as the quantity of acylglyceride or sterol present in the larva. As the concentration of cholestyramine in the diet increased to 6.0%: the number of larval molts increased from 5 or 6 to as many as 7 or 8, the time required for the onset of pupation increased from 11 or 12 to 20 days, and the number of adults that emerged decreased from at least 70 to 0%. The growth and development of the insect may have slowed, at least in part, because this agent reduced the quantity of sterol and glyceride in the tissues of the larva. Niacin also affected the growth and development of the insect. As the concentration of niacin in the diet increased to 5.0%: the number of larval molts increased by 1, the time required for the onset of pupation increased to 21 days, pupal weight decreased significantly, but adult emergence was normal. The growth and development of the insect may have slowed, at least in part, because this agent caused sterol to accumulate in the hemolymph of the larva. A water-soluble component in the hemolymph also increased in the presence of niacin, but there was little or no change in the glyceride content. Further studies are warranted to determine the mode of action of these hypolipidemic agents in H. zea.
    Additional Material: 3 Ill.
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