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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    Journal of Mathematical Physics 30 (1989), S. 1606-1613 
    ISSN: 1089-7658
    Source: AIP Digital Archive
    Topics: Mathematics , Physics
    Notes: Explicit computation for a Kawamoto-type equation shows that there is a rich associated symmetry structure for four separate hierarchies of nonlinear integrodifferential equations. Contrary to the general belief that symmetry groups for nonlinear evolution equations in 1+1 dimensions have to be Abelian, it is shown that, in this case, the symmetry group is noncommutative. Its semisimple part is isomorphic to the affine Lie algebra A(1)1 associated to sl(2,C). In two of the additional hierarchies that were found, an explicit dependence of the independent variable occurs. Surprisingly, the generic invariance for the Kawamoto-type equation obtained in Rogers and Carillo [Phys. Scr. 36, 865 (1987)] via a reciprocal link to the Möbius invariance of the singularity equation of the Kaup–Kupershmidt (KK) equation only holds for one of the additional hierarchies of symmetry groups. Thus the generic invariance is not a universal property for the complete symmetry group of equations obtained by reciprocal links. In addition to these results, the bi-Hamiltonian formulation of the hierarchy is given. A direct Bäcklund transformation between the (KK) hierarchy and the hierarchy of singularity equation for the Caudrey–Dodd–Gibbon–Sawada–Kotera equation is exhibited: This shows that the abundant symmetry structure found for the Kawamoto equation must exist for all fifth-order equations, which are known to be completely integrable since these equations are connected either by Bäcklund transformations or reciprocal links. It is shown that similar results must hold for all hierarchies emerging out of singularity hierarchies via reciprocal links. Furthermore, general aspects of the results are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 63 (1988), S. 2104-2109 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: A new diffusion technique in InP using a Zn3P2 layer as the diffusion source with rapid thermal annealing is evaluated, and a number of interesting features are discussed. A p+ layer can only be achieved at temperatures ranging between 500 and 550 °C with a 15-s minimum diffusion time. Diffusivity is calculated and it is comparable with that of furnace diffusion. However, in order to form a shallow layer, there should not be any high temperature treatment or any other cause for the redistribution of Fe or dopant. Annealing at 850 °C for 15 s prior to diffusion moves the carrier profile from 3000 to 6000 A(ring) deep, and the second diffusion front extends to 2.4 μm for the semi-insulating InP substrate. Similar results are obtained on MOCVD grown semi-insulating Fe:InP epiwafer. Diffusion performed on samples without preannealing resulted in two diffusion fronts and a 2.8-μm deep second diffusion front is observed for a diffusion performed on a preannealed epiwafer.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 483-483 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 58 (1987), S. 1709-1723 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: A pulsed EPR spectrometer is described. This spectrometer is designed for the study of relaxation times of dilute solutions of samples in common solvents as a function of temperature both above and below room temperature. Resolution of pulse widths and spacings is 1 ns. Both continuous wave (cw) and pulsed electron spin-echo studies can be done on the same sample on the same spectrometer. Details of component choices and timing synchronization are provided. Phase alternation sequences for eliminating unwanted echoes are described. Examples of performance of the spectrometer are presented.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Review of Scientific Instruments 57 (1986), S. 2584-2592 
    ISSN: 1089-7623
    Source: AIP Digital Archive
    Topics: Physics , Electrical Engineering, Measurement and Control Technology
    Notes: This paper describes an assessment of the behavior of a differential scanning calorimeter and the development of satisfactory calibration, operation, and data reduction procedures, which depend on performance characteristics of the individual instrument. Factors that contribute to thermal lag are identified; suggestions for evaluating and compensating for it are given.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 7250-7250 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 86 (1987), S. 1348-1355 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Canonical variational transition state theory is used to study the kinetics of Li++(CH3)2O association. Transition states and rate constants are calculated for a complete analytic potential energy surface which includes all inter- and intramolecular coordinates, and for an ion–dipole/ion–induced-dipole two-body potential. These surfaces have a single transition state at each temperature. Anisotropy in the polarizability is found to have a negligible effect on the association transition states and rate constants. The canonical variational transition state theory rate constants are in good agreement with those calculated by other formalisms.
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  • 8
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 84 (1986), S. 3783-3787 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Canonical variational transition state theory rate constants are calculated for Li++H2O→Li+(H2O) recombination. Temperature dependence transition states are determined by finding the maxima in the free energy along the reaction path. Only one maximum is found at each temperature. The transition state theory rate constants are larger than those determined in a previous quasiclassical trajectory study of Li++H2O recombination. This results from a dynamical recrossing of the transition state dividing surface in the trajectory calculations.
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  • 9
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 83 (1985), S. 548-551 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Oxygen isotope shifts on the 13C chemical shifts and carbon isotope shifts on the 17O chemical shifts in carbon monoxide and carbon dioxide are reported. Using models developed by Jameson, shielding derivatives with respect to bond lengths can be calculated using the measured isotope shifts. For carbon monoxide, the derivatives were calculated to be [∂σ (13C)/∂r]e =−456±15 ppm/A(ring) and [∂σ (17O)/∂r]e =−1150±130 ppm/A(ring). Although earlier coupled Hartree–Fock calculations give a much lower value for [∂σ (17O)/∂r]e, recent ab initio calculations for carbon monoxide agree very well with our experimental results. Furthermore, the observed 18O/16O iostope shift is similar to values measured previously for a series of metal carbonyls. For carbon dioxide the iostope shift gives [∂σ (13C)/∂r]e =−214±17 ppm/A(ring) which is in excellent agreement with the value obtained from a recent variable temperature gas phase NMR study. In addition, scalar spin–spin coupling constants, 1J(13C,17O) were measured to be 16.4±0.1 Hz in carbon monoxide and 16.1±0.1 Hz in carbon dioxide. To our knowledge, these are the first directly measured carbon–oxygen coupling constants to be reported in the literature. From general trends in the periodic table, it seems likely that the sign of these coupling constants is positive.
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