ALBERT

All Library Books, journals and Electronic Records Telegrafenberg

feed icon rss

Your email was sent successfully. Check your inbox.

An error occurred while sending the email. Please try again.

Proceed reservation?

Export
Filter
  • Wiley-Blackwell  (45)
  • American Meteorological Society (AMS)
  • 1985-1989  (42)
  • 1930-1934  (3)
Collection
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 30 (1986), S. 529-540 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Extensional elastic moduli have been calculated for several organic high polymers based on the modified neglect of diatomic overlap (MNDO) Hamiltonian. Standard semiempirical methods, by application of the Born-von Karman boundary conditions, can be used to calculate heats of formation of polymer chain sections, or computational unit cells, called clusters. Unit cell heats of formation at elongated translation vectors, combined with experimental or estimated densities, allow for the calculation of elastic moduli. Two potential sources of error were identified: (a) finite geometry optimization can result in pseudorandom errors in the calculated heat of formation, and (b) anharmonic distortion can become significant at large strains. Errors due to both causes can typically be minimized if strains between 3 and 10% are selected. As expected, the calculated moduli, although higher than those observed experimentally, agree with longitudinal values for perfectly oriented systems.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 35 (1989), S. 305-313 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: It is shown that infinite long polyacene chains may have three energetically close but structurally distinct isomers (a symmetrical, sym, form and two lower symmetry forms: one with double bonds in a trans and another isomer with double bonds in a cis pattern). The energetics is based on solid state MNDO theory. We discuss that the symmetrical form has a substantial energy gap Eg in the Hartree-Fock approach owing to exact exchange terms, which are nonlocal. Broken symmetry Hartree-Fock (HF) solutions for polyacene are also described. An angularly distorted structure suggested earlier on Jahn-Teller grounds is found to be energetically not favorable.
    Additional Material: 4 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 3
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The factors relating to measuring the position of the methyl deformation mode at about 1378 cm-1 with sufficient precision to permit its use for the identification of the different branches present in the various types of “linear” low density polyethylene(as manufactured by the copolymerization of ethylene and a 1-alkene) have been examined systematically. With a data density of eight points per wavenumber, and the well established subtraction procedure with polymethylene or with a near-linear polyethylene to remove the overlapping methylene deformation band, it is possible to achieve a precision of ±0,15 cm-1. This is ample to distinguish between methyl, ethyl, and butyl or hexyl branches, but not to characterise uniquely these last two. The use of Fourier self-deconvolution to separate the methyl band has also proved very effective. The precision obtainable when these methods are applied to spectra measured with one data point per wavenumber is somewhat lower, but is still adequate for characterisational purposes. The results for a series of polymers containing ethyl branches at various concentrations suggest a small difference for the peak position for branches present in crystalline and amorphous regions.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Morphology 185 (1985), S. 101-114 
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Paraffin sections of an ontogenetic series of embryos of the viviparous lizard Gerrhonotus coeruleus and the oviparous congener G. multicarinatus reveal that although general features of the development of the chorioallantoic and yolk sac membranes are similar, differences are evident in the distribution of the chorioallantoic membrane in late stage embryos. An acellular shell membrane surrounds the egg throughout gestation in both species although the thickness of this structure is much reduced in G. coeruleus over that of G. multicarinatus. The initial vascular membrane to contact the shell membrane in both species is a trilaminar omphalopleure (choriovitelline membrane) composed of ectoderm, mesoderm of the area vasculosa, and endoderm. This transitory membrane is replaced by the vascularized chorioallantois as the allantois expands to contact the inner surface of the chorion. Prior to the establishment of the chorioallantois at the embryonic pole, a membrane begins to form within the yolk ventral to the sinus terminalis. This membrane, which becomes vascularized, extends across the entire width of the abembryonic region and isolates a mass of yolk ventral to the yolk mass proper. The outer membrane of the yolk pole is a nonvascular bilaminar omphalopleure (chorionic ectoderm and yolk endoderm). In G. multicarinatus the bilaminar omphalopleure is supported internally by the vascularized allantoic membrane, whereas in G. coeruleus the allantois does not extend beyond the margin of the isolated yolk mass and the bilaminar omphalopleure is supported by the vascularized intravitelline membrane. Both the chorioallantoic placenta (uterine epithelium, chorionic ectoderm and mesoderm, and allantoic mesoderm and endoderm) and the yolk sac placenta at the abembryonic pole (uterine epithelium, chorionic ectoderm, and yolk sac endoderm) persist to the end of gestation in G. coeruleus.
    Additional Material: 22 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 34 (1987), S. 721-735 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Both the rate and apparent equilibrium of propane sorption in glassy polystyrene were increased after swelling the polymer by exposure to a highly sorbing vapor. Cyclic sorption experiments revealed that the increase in rate and apparent equilibrium of sorption due to the preswelling treatment decayed only during vacuum aging. The presence of low levels of propane in the polymer during aging, however, appeared to arrest the decay in sorption capacity. These composite results, taken in conjunction with the results of previous work in our laboratory, suggest that the component of the total sorption which resides in nonequilibrium, distended interchain gaps retards the chain motions which otherwise lead to consolidation of the dilated glass.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 6
    Electronic Resource
    Electronic Resource
    Bognor Regis [u.a.] : Wiley-Blackwell
    Journal of Polymer Science Part A: Polymer Chemistry 25 (1987), S. 1295-1307 
    ISSN: 0887-624X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: ESCA and contact angle measurements were used to characterize the surfaces of Polyethylene and polypropylene films exposed to SF6, CF4, and C2F6 plasmas. None of these gases polymerized in the plasma. However, all plasma treatments grafted fluorinated functionalities directly to the polymer surfaces. SF6 plasmas graft fluorine atoms to a polyolefin surface. CF4 plasmas also react by a mechanism dominated by fluorine atoms, but with some contribution from CFx-radical reactions. Although C2F6 does not polymerize, the mechanism of grafting is still dominated by the reactions of CFx radicals. For all gases studied, the lack of polymerization is attributed to competitive ablation and polymerization reactions occurring under conditions of ion bombardment.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 7
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Cell Motility and the Cytoskeleton 14 (1989), S. 3-11 
    ISSN: 0886-1544
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 8
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Thirty seven of the thirty eight isomers of tetrachlorodibenzofuran (TCDF) have been synthesized by unambiguous routes, and purified. The 1,2,8,9-TCDF isomer could not be thus prepared, and attempts to make it by pyrolysis of appropriate precursors also failed. Retention characteristics of TCDFs under gas chromatographic conditions were determined, and found to agree well with those predicted by an existing mathematical model derived from data obtained for TCDF isomers prepared by more ambiguous procedures. Mass spectral characteristics were also obtained, particularly relative response factors for the molecular ions of the TCDF isomers under electron ionization (EI) conditions. A discussion of the likely transferability of these relative response factors between mass spectrometers of different types is included. Chemical ionization (CI) mass spectra were also obtained, for both positive and negative ions. These CI spectra yielded little structural information not available from the EI data, and problems of lack of sensitivity and of reproducibility render them less suitable for trace analysis of TCDFs. Some unusual ion chemistry was observed under CI conditions, which can be rationalized in terms of pre-ionization attack on the TCDF molecule by free radicals in the source.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 9
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 1977-1985 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A finite-element method is given for efficient simulation of multiphase distillation systems. Breakpoints are adaptively located to coincide with phase discontinuities. Thermodynamic criteria for the states at these discontinuities are included in the equation system. The adjustable breakpoint locations are calculated simultaneously with the other system variables by global Newton iteration. Worked examples demonstrate the accuracy and efficiency of the method.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
  • 10
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 33 (1987), S. 2008-2016 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Mass transfer rates in laminar and turbulent nonseparated boundary layers are asymptotically expanded for small values of the diffusivity DAB, with a uniform state on the mass transfer surface. Results for heat transfer follow by analogy. The thermal or binary Nusselt number at small net mass transfer rates is given asymptotically by a generalized penetration expression \documentclass{article}\pagestyle{empty}\begin{document}$$ \langle Nu\rangle \, = \,a_{00} Pe^{1/2} \, + \,a_{01} Pe^0 \, + \,.\,.\,.\,{\rm (A)} $$\end{document} for short times, or for boundary layers that duplicate the surface tangential motion. For flows past rigid interfaces, the long-time average of 〈Nu〉 is given asymptotically by a generalized Chilton-Colburn relation \documentclass{article}\pagestyle{empty}\begin{document}$$ \langle \overline {Nu} \rangle \, = \,b_{00} Pe^{1/3} \, + \,b_{01} Pe^0 \, + \,.\,.\,.\,{\rm (B)} $$\end{document} in regions of nonrecirculating motion. The measurable functions aij and bij depend only on the system shape and laminar or turbulent velocity field. Formal expressions for a00 are given, and an expression for b00 in steady flows. These results agree well with data on mass transfer operations in tubes, packed beds, and fluid-fluid contactors.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    Location Call Number Expected Availability
    BibTip Others were also interested in ...
Close ⊗
This website uses cookies and the analysis tool Matomo. More information can be found here...