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Identification of the high efficiency 127μm FIR laser line of13CD3OH (1988)

Mukhopadhyay, I. ; Lees, R. M. ; Lewis-Bevan, W.

Springer

International journal of infrared and millimeter waves 9 (1988), S. 545-553

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ISSN: 1572-9559

Keywords: far-infrared (FIR) lasers ; FIR spectroscopy ; methanol

Source: Springer Online Journal Archives 1860-2000

Topics: Physics

Notes: Abstract An assignment is proposed for the strong 127.0 μm far-infrared (FIR) line of13CD3OH known to be pumped with very high efficiency by the 10P(8) CO2 laser line. On the basis of spectroscopic clues derived from calculated molecular parameters and energies for13CD3OH, the 127 μm line is identified as the (nτK,J)=(116,17)→(125, 16) transition, and its companion 462.8 μm line as the (116,17)→(116,16) transition. Proposed partial assignments and predictions are also discussed for a number of other FIR laser lines in13CD3OH, CD3OH, CD3OD, CH3OD, CH3OH and13CH3OH.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1007/BF01013288

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