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  • Chemical Engineering  (2)
  • Wiley-Blackwell  (2)
  • American Institute of Physics (AIP)
  • De Gruyter
  • Wiley
  • 1985-1989  (2)
  • 1950-1954
  • 1
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 26 (1986), S. 543-553 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A systematic design of the classical “coat hanger” die is proposed and tested experimentally. The objectives of the design are 1. distribution of the polymer over the width of the die before it reaches the final lip section for thickness adjustment, 2. invariance of distribution to flow rate, 3. invariance to changes in polymer viscosity, and 4. uniform average residence time. The die design is based on a flow model which assumes power-law viscosity, steady shear flow In each cross-section, uniform temperature, and separation of the flows into a manifold component and a component in a slit section of uniform height. The design corrects for an oversimplification of the pressure gradient that was applied in previous studies; and it differs from previous designs by suggesting a rectangular cross-section for the manifold. Applications to side-fed dies for extrusion blow molding and to a sheet extrusion die achieved uniform distribution and did not require any additional flow corrections (such as choker bars or flexible lips). With the new design, the lip region of the die can freely be used for thickness control, fine tuning, or further shaping of the extrudate.
    Additional Material: 16 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 25 (1985), S. 857-862 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Silane-grafted polyethylene materials are processed in conventional thermoplastic fabrication machines. The shaped articles are then crosslinked in water by the formation of Si-O-Si crosslinks. This paper represents studies on the crosslinking progress in different environments at various temperatures. Molecular orientation is shown to become permanent and mostly irrecoverable even at 150°C, in the silane-grafted solid state crosslinked specimens (the crosslinking temperature in water is well below the polymer melting temperature). These frozen molecular orientations have a significant effect on the tensile properties of the crosslinked materials causing higher yield stresses and lower elongations at break. The thermal and tensile properties of some silane-grafted crosslinked polyethylene samples and peroxide-crosslinked materials are compared and analyzed.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
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