ISSN:
0022-3832
Keywords:
Chemistry
;
Polymer and Materials Science
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
The preparation and properties of copolymers of three perfluoroalkyl propenyl ketones with different 1,3-dienes are described. Emulsion copolymerization at 50°C. and at 5°C. of perfluoromethyl, perfluoropropyl, and perfluoroheptyl propenyl ketones with 1,3-dienes, such as butadiene, 1, 1,2-trifluoro-3-chlorobutadiene, 1,1,2-trifluorobutadiene, and isoprene, has been accomplished and many of the products have exhibited elastomeric properties. Attempted copolymerization of perfluoropropyl propenyl ketone with 1,1,2-trifluoro-3,4,4-trichlorobutadiene or 1,1,2-trifluoro-3,4-dichlorobutadiene did not yield any polymeric products at either 50°C. or at 5°C. Qualitative determinations of thermal stability and solvent resistance have been made for some of the ketone/diene copolymers for comparison with commercial cold GR-S rubber.
Additional Material:
6 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/pol.1958.1203312638
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