ISSN:
0749-1581
Keywords:
Hexahydrocannabinol
;
13C-13C 2D correlation
;
1H-13C 2D ‘reverse’ correlation
;
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Two-dimensional carbon-carbon correlated spectra (2D-INADEQUATE) and proton-carbon correlated spectra obtained with proton detection have been used to determine the absolute configuration and conformation of a hexahydrocannabinol derivative obtained with highly stereocontrolled synthesis. From the proton-proton coupling constants the junction between rings B and C was found to be trans and the relative stereodisposition of C-10a, C-9 and C-6a was deduced to be R.
Additional Material:
3 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/mrc.1260251213
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