ISSN:
0570-0833
Keywords:
Ketenimines
;
Carbene ligands
;
Isocyanides
;
Carbocycles
;
Heterocycles
;
Synthetic methods
;
Chemistry
;
General Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Ketenimine complexes are readily available in great variety by reaction of isocyanides with carbene complexes. They have proven to be useful building blocks in new synthetic approaches to carbocyclic and N-heterocyclic four-, five-, and six-membered rings. The reactions involve new metal-induced bond formation patterns of the ketenimine ligands, which can be influenced across a wide range by varying the following five parameters: the metal, the ligands, and the three substituents on the N=C=C unit.
Additional Material:
8 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/anie.198814561
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