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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 18 (1989), S. 733-737 
    ISSN: 0887-6134
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A method of fully automating the analysis of routine samples using probe introduction techniques has been designed and developed. Unattended 24 h operation has dramatically increased the ability to process large numbers of samples and has freed much of an operator's time to perform other tasks.
    Additional Material: 6 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 21 (1970), S. 336-342 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Description / Table of Contents: Recent developments in ferritic stainless steelsThe pitting resistance of ferritic stainless steels in HCl is visibly improved by Mo, in particular in the case of vacuum-melted material. In this context the ratio Cr:Mo = 25:2 is superior ta Cr:Mo = 17:3; addition of Mo prevents, beyond that, crevice corrosion. Ti increases resistance in the Strauß test but not in the Huey test, while Nb turns out to have a positive effect in either test. Steels containing Cr: Mo = 17:l are certainly still susceptible to pitting, but no longer to stress corrosion cracking in boiling MgCl2, solution; stress corrosion cracking is not observed in 55% boiling Ca(NO3)2, and 25% boiling NaOH, but after annealing at 980 °C intercrystalline corrosion takes place. The test duration required for establishing cracking susceptibility is considerably shorter with ferritic than with austenitic steels (100 and 1000 to 2000 hours respectively).
    Notes: Die Beständigkeit von nichtrostenden ferritischen Stählen gegen Lochfraß in HCl wird durch Mo deutlich verbessert, besonders, wenn es sich un vakuumerschmolzenes Material handelt. Hierbei ist die Kombination Cr :Mo 25 :2 besser als 17:3; der Mo-Zusatz verhindert außerdem Spaltkorrosion. Ti erhöht die Beständigkeit im Strauß-Test, nicht hingegen im Huey-Test, während Nb sich in beiden Medien als günstig erweist. Stäble mit Cr:Mo 17:l sind zwar noch anfällig fur Lochfraß, nicht mehr hingegen für Spannunnsrißkorrosion in kochendem MgCl2; auch in kochendem Ca-Nitrat (55%) oder NaOH (25%) tritt keine Spannungsrißkorrosion auf; doch wird nach Glühen bei bei 980°C interkristalline Korrosion beobachtet. Die zur Prüfung der Rißbildungsneigung erforderliche Versuchsdauer ist für die ferritischen Stähle wesentlich kürzer als für austenitische (100 gegen 100 bei 2000 Std).
    Additional Material: 4 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Electroanalysis 1 (1989), S. 1-11 
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A review of the various simultaneous ESR-electrochemical techniques that have been developed is presented. Special advantages and disadvantages of the stationary and flow-through cell configurations are described. A critical evaluation of the in situ ESR-electrochemical cells developed to date has also been made. A selected survey of applications is presented to illustrate the wide range of chemical information on redox reactions which can be obtained by the simultaneous ESR-electrochemical method.
    Additional Material: 4 Ill.
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  • 4
    ISSN: 1040-0397
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Gold and platinum ultrathin ring microelectrodes (0.1-0.5 mm thick, 1.5-4 mm diameter) were made by sputtering, from fired metalloorganic paint, and from foil for use as sensors in a thick-layer wall-jet flow cell. An end-on array of three 0.1 μm × 0.5 mm gold band electrodes were mounted parallel to the flow direction in a thin-layer channel cell. These ultrathin sensors, along with a jet-centered carbon microdisk, were evaluated in the amperometric flow-injection mode for temporal stability, calibration sensitivity, detectivity, background signal, and flow rate dependence of the analytical signal using ferrocene samples in acetonitrile containing 10-4-10-2 M TEAP. The detectivity of gold paint ring electrodes made on borosilicate glass was 3-6 nM, an order of magnitude lower than any of the other electrodes tested. Analytical signals from gold paint and foil rings and the carbon microdisk had the best temporal stability. The current for the ultrathin band array in a channel cell was flow rate-independent, and the exponential dependence of cell current on flow rate was 0.11-0.14 for ultrathin rings in the thick-layer wall-jet mode.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 9 (1971), S. 1777-1778 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-1: Polymer Chemistry 9 (1971), S. 1775-1775 
    ISSN: 0449-296X
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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