Electronic Resource
College Park, Md.
:
American Institute of Physics (AIP)
The Journal of Chemical Physics
82 (1985), S. 4777-4787
ISSN:
1089-7690
Source:
AIP Digital Archive
Topics:
Physics
,
Chemistry and Pharmacology
Notes:
The influence of an internal vibrational resonance on the IR multiphoton excitation of a model molecular system is studied numerically using Floquet theory. It is shown that a classical resonance zone can bottleneck photon absorption. The bottleneck effect is easily understood in terms of the strongly perturbed phase space topology near a classical resonance zone and the corresponding distortions in quantum mechanical eigenstates and eigenvalues of the field-free Hamiltonian.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1063/1.448695
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