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  • Chemistry  (102)
  • Polymer and Materials Science  (76)
  • Analytical Chemistry and Spectroscopy  (23)
  • 1985-1989  (48)
  • 1975-1979  (43)
  • 1970-1974  (34)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Introduction (1989)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 1-1 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760290102
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  • 2
    Electronic Resource
    Electronic Resource
    Polyesters II: A review of phase behavior in binary blends: Amorphous, crystalline, liquid crystalline, and on transreaction (1989)
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 29 (1989), S. 55-62 
    Details
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Thermal and mechanical studies on many linear polyesters have revealed their behavior in crystalline, liquid crystalline, and amorphous phases. Their phase behavior in binary compositions has also been studied by a range of additional techniques and in combinations including the polycarbonate of bisphenol-A. Regions of amorphous compatibility and incompatibility have been identified and measures made of transition temperature changes with composition. The conditions for transreaction have also been determined and the properties measured for the resultant new copolymers.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pen.760290110
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  • 3
    Electronic Resource
    Electronic Resource
    Dynamic and steady-shear melt rheology of and ethylene-methacrylic acid copolymer and its salts (1970)
    New York : Wiley-Blackwell
    Journal of Polymer Science Part A-2: Polymer Physics 8 (1970), S. 277-287 
    Details
    ISSN: 0449-2978
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Studies have been made on the dynamic and steady-shear melt rheology of an ethylene-methacrylic acid copolymer and two of its salts obtained by partial neutralization with sodium and with calcium bases. Measurements were made with a Weissenberg rheogoniometer over a broad range of shear rates and frequency in the temperature interval mainly from 100 to 160°C. The temperature coefficients of dynamic and steady shear viscosity are evaluated at both constant shear rate and constant stress. Likewise, complex dynamic viscosities and apparent high steady-flow viscosities and intercompared at equivalent frequencies and shear rates. The un-ionized acid copolymer shows good correlation between the frequency dependence of the complex viscosity and the shear rate dependence of the apparent viscosity. This is not true for either the sodium salt or the calcium salt. These results are consistent with the two-phase structural model for these materials, i.e., a matrix of hydrocarbon in which are embedded ionic domains.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1970.160080206
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  • 4
    Electronic Resource
    Electronic Resource
    A mathematical model for polymerization of isoprene with n-butyllithium in hexane (1974)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 18 (1974), S. 1805-1819 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Isoprene was polymerized in batch reactors by use of bottle polymerization techniques at 30°, 40°, and 50°C at concentrations from 1 to 5 molar. Butyllithium concentration was varied from 0.005 to 0.03 molar. Isoprene and n-butyllithium conversions and molecular weight distributions were determined for different reaction times. Rate equations for the initiation and propagation reactions are presented. The importance of the association reactions in obtaining a narrow molecular weight distribution is illustrated.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1974.070180618
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  • 5
    Electronic Resource
    Electronic Resource
    Irregularities in steady flow for non-newtonian fluids between cone and plate (1979)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 23 (1979), S. 953-965 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Flow irregularities have been visually observed in solutions of polyacrylamide of high molecular weight on shear in a cone-and-plate rheometry (gap angle 2.3°). This anomalous flow was found to depend on molecular weight, concentration, and solvent. The onset of flow irregularities were generally at shear rates 〈 5 sec-1. A dimensional analysis shows that the elastic component of the fluid is responsible for the anomalous flow. The onset of flow irregularities has been predicted from measurements of recoverable strain as a function of shear stress.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1979.070230401
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  • 6
    Electronic Resource
    Electronic Resource
    The preparation and tensile properties of polyethylene composites (1978)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 22 (1978), S. 3249-3265 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Single polymer composites have been prepared using different morphologies of polyethylene as matrix and as the reinforcement. Depending on annealing conditions, the ultraoriented fibers used as reinforcement can have higher melting points (ca. 139°C) than the matrix made from the same conventionally crystallized high-density polyethylene (ca. 132°C) or from low-density polyethylene (ca. 110°C). The optimum temperature has been assessed for bonding to occur by growth of transcrystalline regions from the melt matrix without considerable modulus reduction of the annealed ultraoriented and reinforcement fiber or film. Pullout tests have been used for determining the interfacial shear strength of these single polymer composites. The interfacial shear strength for the high-density polyethylene films embedded in a low-density polyethylene matrix is 7.5 MPa and for high-density polyethylene self-composites is 17 MPa. These values are greater than the strength for glass-reinforced resins. The strength is mainly due to the unique epitaxial bonding which gives greater adhesion than the compressive and radial stresses arising from the differential shrinkage of matrix and reinforcement. The tensile modulus of composites prepared from uniaxial and continuous high-density polyethylene films embedded in low-density polyethylene obeys the simple law of mixtures and the reinforced low-density polyethylene modulus is increased by a factor of 10. High strength cross-ply high-density-polyethylene - low-density-polyethylene laminates have also been prepared and the mechanical properties have been studied as the film orientation is varied with respect to the tensile axis.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1978.070221119
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  • 7
    Electronic Resource
    Electronic Resource
    Optical characterization of solid-state coextruded PET (1985)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 30 (1985), S. 251-262 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Amorphous poly(ethylene terephthalate) has been solid state coextruded to a series of draw ratios up to 4.4 at 50, 60, 70 and 90°C. These uniaxially drawn samples have been examined by optical microscopy and light scattering and for increases in crystallinity and birefringence as a function of draw ratio and draw temperature. The birefringence for PET may be among the highest yet reported - 0.21.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1985.070300120
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  • 8
    Electronic Resource
    Electronic Resource
    Evaluation of free and hydrostatic equibiaxial deformation of poly(ethylene terephthalate) by trirefringence measurement (1987)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 33 (1987), S. 1517-1523 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Understanding the deformation behavior of an amorphous thermoplastic, e.g., poly(ethylene terephthalate) (a-PET) and one of semicrystallinity, viz., i-PP, can be is of both fundamental and practical importance. Much has been done to study the influence of temperature and strain, but not the influence of deformation conditions on the three-dimensional orientation of many thermoplastic. In this study we consider the incremental effect of hydrostatic pressure and process geometry on strain-induced deformation. a-PET has been free drawn (i.e., no hydrostatic pressure) isothermally on a tenter frame device. The hydrostatic, equibiaxial deformation was achieved by a forging process involving squeezing between two circular plates. These two processes have been carried out at a series of deformation rates, with the three-dimensional refractive index measurements having been made on the PET and i-PP films using a modified Abbe refractometer, as per Samuels. The reported trirefringence measurement provides a sensitive scale for the planar deformation.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1987.070330508
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  • 9
    Electronic Resource
    Electronic Resource
    Melt transcrystallization of polyethylene on high modulus polyethylene fibers (1988)
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 35 (1988), S. 1945-1953 
    Details
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A polytheylene composite was prepared and tested. It was consisted of a high-density polyethylene (HDPE) matrix and uniaxial gel-spun high-modulus PE fiber. Aided by the similarity between matrix and fiber, transcrystallization of HDPE melt on the PE fiber surface was generated. Nucleating agents were not employed. The transcrystalline growth of HDPE on the PE fiber surface was found to consist of an inner and an outer zone. The inner zone, 2-3 μm thick, is composed of HDPE crystals nucleated on the PE fiber surface. Photomicrographs showed a well-defined region of row-nucleated HDPE on the surface of PE fiber. This means the fibrils of HDPE were found to grow out from the PE fiber axis and HDPE crystallites are oriented in planes perpendicular to the PE fiber axis. The fiber in the composite induced the transcrystalline growth of HDPE on the PE fiber surface at higher temperature than on cooling the melt. For 36 wt% fiber, the increase was 2.5°C, also resulting in ∼ 10% more crystals. Crystallization of a composite with 50 wt% fiber at 124°C involved two steps: The first a fast transcrystallization of HDPE on the PE fiber surface followed by the bulk crystallization of the HDPE.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/app.1988.070350720
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  • 10
    Electronic Resource
    Electronic Resource
    Morphology of polymers, B. Sedlacek, Ed. de Gruyter, Berlin and New York, 1986, 797 pp. Price: $189.00 (1987)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Letters Edition 25 (1987), S. 267-267 
    Details
    ISSN: 0887-6258
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1987.140250610
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