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  • 1990-1994  (15)
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  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 198 (1992), S. 39-49 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wird eine Ultraschall-Meßmethode vorgestellt, mit der sich fünf voneinander unäbhangige Elästizitatskonstanten von uniaxial symmetrischem Material bestimmen lassen. Für die Messung werden nur fünf Ultraschallausbreitungsgeschwindigkeiten benötigt. Vermessen wurden spritzgegossene Composite aus Polyphenylensulfid, Polyarylethersulfon mit Cardo-Seitengruppen, kurzen Kohlefasern und RUB. Die Ergebnisse zeigen eine enge Beziehung zwischen den elastischen Eigenschaften und der Struktur der Materialien auf.
    Notes: The paper makes an approach to the determination of the five independent elastic constants of uniaxial symmetric material with the ultrasonic immersion technique. Only five ultrasonic wave velocities are required during measurement. The elastic constants of the moulded composites comprised of poly(phenylene sulfide), poly(aryl ether sulfone) with cardo side groups, short carbon fiber and carbon black are measured by using the suggested treatment. The results exhibit a close relationship between the elastic properties and the structure of the materials.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Angewandte Makromolekulare Chemie 222 (1994), S. 147-163 
    ISSN: 0003-3146
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Es wurde versucht, Sisalfasern zu kostengünstigen Kohlefasern zu carbonisieren. Vorbehandlung, Pyrolyse- und Carbonisierungsvorgang sowie Struktur und Eigenschaften der gebildeten Produkte wurden untersucht. Anwendungsmöglichkeiten für die aus Sisal hergestellten Kohlefasern mit mäßigen mechanischen Eigenschaften werden vorgeschlagen.
    Notes: An attempt to convert natural sisal fiber into low cost carbon fibrous materials was made. The pretreatment, pyrolysis and carbonization processes of raw sisal fiber as well as structure and properties of the resultant product were investigated. It was found that the sisal-based carbon fiber with moderate mechanical performance can be manufactured under the conditions applied. In addition, the application of the obtained sisal-based carbon fiber serving as functional material is presented.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 193 (1992), S. 1745-1752 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The spherulitic morphology of poly(ether-ether-ketone)Systematic name: poly(oxy-1, 4-phenyleneoxy-1,4-phenylenecarbonyl-1,4-phenylene). (PEEK) has been studied by using polarizing light microscopy, IR and differential scanning calorimetry. It has been found that in distinct cases the spherulites of PEEK show radiated or banded morphology, which can change from one to another upon thermal treatment. The process was found to be reversible and also affected by the film thickness.
    Additional Material: 6 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 192 (1991), S. 293-299 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The temperature and frequency dependence of internal friction of a polyaryl ether sulfone with cardo side groupsSystematic name: poly(phthalidylidene-1,4-phenyleneoxy-1,4-phenylenesulfonyl-1,4-phenyleneoxy-1,4-phenylene). (1) are measured using a multi-function torsion pendulum below the glass transition temperature (531 K). Two relaxation peaks are observed at 328 K and 150 K (for 0,1 Hz). The elementary processes of the two relaxations are found to be different from each other: the relaxation at higher temperature is an ordering process and that at lower temperature is a disordering one.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 47 (1993), S. 45-52 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polyacrylonitrile fiber was treated with hydroxylamine to form a chelating fiber containing the amidoxime group with high adsorption capacity to the Au3+ ion (up to 626 mg/g, when the nitrile group conversion reaches 53.7%), reasonable mechanical properties, and good thermal stability; the relationship among reaction conditions, fiber structures, and properties were investigated. The amidoxime group content rapidly increases to a steady value with increasing reaction time or HONH2 • HCl concentration, the fiber strength drops linearly with increasing reaction time, when the reaction takes place at the temperature where the morphology and order structure begins to be destroyed, and the amidoxime group content increases significantly, while fiber strength decreases remarkably. It is suggested that, to prepare a chelating fiber with high adsorption capacity and reasonable mechanical property, the reaction could be carried out at temperatures from 70 to 75°C, time of about 30 min, and concentration around 75 g/L. © 1993 John Wiley & Sons, Inc.
    Additional Material: 10 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 49 (1993), S. 1635-1638 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Metallic gold was extracted directly from a solution containing Au(III) ion by a reactive fiber with the amidoxime group. It is concluded that in the solution containing Au(III), Cu(II), Zn(II), and Cr(III) the reactive fiber presents high selectivity to Au(III). During the adsorption process, the adsorbed Au(III) is partially reduced into spongy metallic gold and the amidoxime group is finally oxidized into the carboxyl group. © 1993 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 52 (1994), S. 1279-1291 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The mechanical property and fracture morphology of glass fiber- (GF) and carbon fiber- (CF) reinforced polysulfone (PSF) blends with bis (4-(4-ethynyl phenoxy) phenyl) sulfone (ATS-C) have been investigated. Experimental results show that the tensile and flexural properties and impact strength of GF-reinforced ATS-C/PSF composites decrease as the processing temperature or/and the processing time increase, but CF-reinforced ATS-C/PSF composites exhibit better mechanical properties. Although interlaminar shear strenght (ILSS) for fiber-reinforced ATS-C/PSF composites decreases, scanning electron microscopy (SEM) observation of fracture surface indicates that the fractural model of fiber-reinforced PSF composites changes from the interfacial debonding fracture to the matrix fracture at the interfacial region with addition of ATS-C and the increase of the processing temperature. The end-use temperature of polysulfone can be retained and solvent resistance of polysulfone can be improved due to the formation of a semi-interpenetrating polymer network. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 1461-1468 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Four kinds of amino-group-containing chelating fibers were prepared by reacting diethylenetriamine, diethanolamine, diethylamine, and aminopyridine, respectively, with a grafted fiber PVA-g-GMA containing epoxy groups. The γ-ray preirradiation initiated graft copolymerization of GMA onto PVA fiber, the functionalization of the grafted fiber PVA-g-GMA with amino compounds, and the adsorption properties of the obtained chelating fibers were systematically investigated. It is concluded that with increasing monomer concentration, reaction time, and temperature, the grafting percentage increases significantly. In the functionalization of the grafted fiber, reaction time, temperature, solvent, and amount of amine used greatly influence the reaction. 1,4-Dioxane is a reasonable solvent for the reaction. The chelating fibers present great adsorption amounts and high adsorption rates for Cu2+ ion and Au3+ ion. Among the chelating fibers, the fiber with diethylenetriamine group is the most reasonable chelating fiber for the adsorption of Cu2+ and Au3+. The chelating fibers present good selectivities for Cu2+ in the solution with Cu2+, Mn2+, Ni2+, Co2+, and Zn2+, while presenting quite high selectivities for Au3+ ion in the solution with Cu2+, Au3+, Zn2+, and Cr3+ ions. The chelating fiber with diethanolamine or diethylamine can reduce the adsorbed Au3+ into metallic gold. © 1994 John Wiley & Sons, Inc.
    Additional Material: 11 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 53 (1994), S. 1653-1661 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The dynamic mechanical behavior, phase separation, and morphology of high-performance semi-interpenetrating polymer network (semi-IPN) obtained from acetylene-terminated sulfone (ATS-C) and high-performance thermoplastics have been studied by torsional braid analysis (TBA) and scanning electron microscopy (SEM). All the ATS-C/thermoplastic blends studied are compatible before curing. The addition of ATS-C results in a dramatic reduction in the glass transition temperature (Tg) of the thermoplastic. As the reaction of cure proceeds, the initially compatible blend passes through a stage of partial compatibility to achieve a fully incompatible semi-IPN. SEM observation of the fracturedetched surface reveals the formation of a co-continuous two-phase structure in the semi-IPNs. The connected globule and network morphology of the cured ATS-C phase are dispersed in a matrix of the thermoplastic phase. The size of dispersed particles decreases with increasing Tg of the thermoplastic. The mechanism of phase separation is discussed. © 1994 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 54 (1994), S. 541-551 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: In a fiber/semicrystalline polymer system, interphasial transcrystallinities might form between the fibers and the matrix bulk that is composed of spherulites. By using an analogy method, the Young's modulus Et of transcrystallinities in their growth direction was predicted by a well-known composite modeling theory. It is shown that Et is a function of the polymeric lamellar morphology and crystallinity. It is higher than the Young's modulus Es of the bulk spherulites and positively affects the stiffness of the materials in which the transcrystallinities are formed. The study was focused on poly(ether ether ketone) (PEEK) but with polyethylene (PE) as a comparison. Also, it is demonstrated the various possibilities of the value ET and the ratio ET/Es for different polymeric matrices depending on their lamellar moduli and the amorphous-phase ones. © 1994 John Wiley & Sons, Inc.
    Additional Material: 6 Ill.
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