ISSN:
1436-5073
Schlagwort(e):
X-ray fluorescence spectrometry
;
neural systems
;
fuzzy logic
;
neurofuzzy
;
qualitative analysis
;
spectra interpretation
;
wavelength dispersive
;
expert system
Quelle:
Springer Online Journal Archives 1860-2000
Thema:
Chemie und Pharmazie
Notizen:
Abstract A decision scheme for the interpretation of spectra from wavelength dispersive X-ray fluorescence spectrometry is described that encompasses elements from three areas of artificial intelligence: fuzzy logic, rule based expert systems and neural net technology. After transforming the recorded spectra to line spectra by appropriate background correction a reasoning scheme is applied that takes into account not only the observed spectra, but also the recording conditions and prior spectroscopic information regarding the relative emission probabilities and the usefulness of the different lines for the purpose of element identification. The latter is done on the basis of a previously described scheme to compute conditional a posteriori Bayes probabilities for a “mean matrix”. These different pieces of information are then assembled into a battery of fuzzy rules. The importance of the rules as well as the importance of the X-ray lines is determined in a training process, similar to the one in a feedforward back-propagation network. To further stabilize the results this network is pruned in a second training cycle. This, however, had little effect on the quality of interpretation. The advantages of this approach to the interpretation of X-ray spectra over older ones are numerous: the system adapts itself to better interpret spectra that are of greater importance to a laboratory as these are better represented in the training set; the fuzzy logic is capable of working with incomplete and uncertain knowledge, and the neural network results based on these fuzzy rules is readily interpretable by the X-ray spectroscopist as every rule can be expressed also in natural language as in any classical rule based system.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1007/BF01243608
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