ISSN:
1573-9171
Keywords:
cyclopentadienyllutetium
;
molecular structure
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
Notes:
Abstract Cp* 2Lu(μ-Cl)2 (1) was isolated following the reaction of Cp*Na (Cp* = 1, 3-(Me3Si)2C5H3) with LuCl3 in THF and subsequent treatment with toluene at 80°C. An X-ray structural investigation of1 was performed (MoK α radiation, 2933 reflections,R = 0.020). The crystals are triclinic,a = 10.744(3) Å,b=11.821(2) Å, c=12.966(3) Å, a=71.54(1)°, β=85.32(2)°, γ=74.83(1)°,Z = 2, space groupP-1. Two Lu atoms withdistorted tetrahedral coordination are linked by two chloride bridges with a mean Lu-Cl distance equal to 2.62 Å.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00698446
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