ALBERT

Description: Absolute intensities for the Q-branch of the 4nu-2 - nu-1 + nu-1/2 (20,003-11,101) band in CO2 were measured for the first time. Measurements were performed for lines Q10 to Q28, at temperatures ranging from 385 to 426 K, for pressures from 3 to 40 torr, using our long wavelength tunable diode laser spectrometer. The combination of tunable diode lasers, a White cell, and a blocked impurity band detector made it possible to obtain signal to noise ratios greater than 1000 in the 471/cm spectral region, with about 3 x 10 exp -4/cm spectral resolution. The band strength was found to be 8.6(2) x 10 exp -25 cm/molec at 296 K, and the Hermann-Wallis factor was determined. Comparison with the values listed in the HITRAN 92 data base are presented. Self-, N2- and O2-broadening coefficients were also measured.

Description: The USAF and NASA successfully conducted infrared spectral measurements of the Space Shuttle glow during STS-39. Preliminary analysis indicates that NO, NO(+), OH, and CO produce infrared glow during quiescent orbiter conditions. During orbiter thruster firings the glow intensities in the infrared are enhanced by factors of 10X and 100X with significant changes in spectral distribution. These measurements were obtained with the Spacecraft Kinetic Infrared Test payload which included a cryogenic infrared circular variable filter infrared spectrometer covering the 0.7 to 5.4 microns wavelength region. Approximately 14,000 spectra of Shuttle glow, airglow, aurora, and the orbiter environment were obtained during the eight day mission. The STS-39 Space Shuttle Discovery was launched from the NASA Kennedy Space Center on 28 April, 1991 into a 57-deg inclination circular orbit at an altitude of 260 km.

Description: An observational approach to Planetary Sciences and exploration from Earth applies to a quite limited number of targets, but most of these are spatially complex, and exhibit variability and evolution on a number of temporal scales which lie within the scope of possible observations. Advancing our understanding of the underlying physics requires the study of interactions between the various elements of such systems, and also requires study of the comparative response of both a given object to various conditions and of comparable objects to similar conditions. These studies are best conducted in 'campaigns', i.e. comprehensive programs combining simultaneous coherent observations of every interacting piece of the puzzle. The requirements include both imaging and spectroscopy over a wide spectral range, from UV to IR. While temporal simultaneity of operation in various modes is a key feature, these observations are also conducted over extended periods of time. The moon is a prime site offering long unbroken observation times and high positional stability, observations at small angular separation from the sun, comparative studies of planet Earth, and valuable technical advantages. A lunar observatory should become a central piece of any coherent set of planetary missions, supplying in-situ explorations with the synoptic and comparative data necessary for proper advance planning, correlative observations during the active exploratory phase, and follow-up studies of the target body or of related objects.

Description: The global distribution of ozone in the atmosphere of Mars was determined from Doppler-limited infrared heterodyne spectroscopy measurements at the NASA Infrared Telescope Facility (IRTF) facility during June 3-7, 1988. Mars spectra near two O3 lines arising from the v sub 3 band near 1031.45 cm (-1) were used. The lines were Doppler shifted out of the strong terrestrial ozone absorption spectrum and its effect was removed. Ozone measurements were obtained at eight beam positions over a range of latitudes and local solar zenith angles. The beam size of the planet was 1.4 arcsec. A Martian CO2 line appeared in the spectra and was inverted to retrieve local temperature profiles. Using these temperature profiles, the total ozone column abundance at each position was retrieved by fitting the measured line with synthetic spectra generated by a radiative transfer program. The only previous measurement of ozone at this season was made above the South polar cap by Mariner 7 and revealed an abundance of 10 micron-atm. However, the retrieved O3 column abundances from this investigation are less than 2.2 micron-atm at all positions sampled. These results are consistent with mid-spring abundances predicted by photochemical models of Liu and Donahue, and Shimazaki and Shimizu.

Description: Comet Brorsen-Metcalf was observed on UT 21 to 24 Aug. 1989 using the CRSP spectrometer and the 1.3 meter telescope at Kitt Peak National Observatory. The cometary continuum was detected on all nights. The data are very noisy, due to the short observation window and the untried nature of the instrument. Low resolution (0.0227 micron) spectra show the 3.4 micron C-H stretch feature having a contrast of at most a factor of two to the neighboring continuum. High resolution (0.0031 micron) spectra between 3.4 and 3.6 microns show 1 sigma features that might be attributed to the nu 5 band of formaldehyde (H2CO). Similar spectra of the region between 3.2 and 3.4 microns show one 3 sigma line at 3.34 microns, which is as yet unidentified. Although the cometary spectra were more spatially extended than the spectra of standard stars, no extension of the line emission beyond the continuum was observed.

Description: An observational search for cometary parent molecules using infrared spectroscopy was conducted in the 1 to 5 micron region. The investigation involved two different observing programs, one at moderate spectral resolution and one at fairly high resolution. The lower resolution was used to study cometary spectra in the vicinity of 3.5 micron at wavelength/change in wavelength is approximately or equal to 10(exp 3). Comets P/Brorsen-Metcalf (1989o), Okazaki-Levy-Rudenko (1989r), and Austin (1990c1) were observed with the Cryogenic Spectrometer (CRSP) at Kitt Peak. The detector incorporated an InSb array with 58 spatial elements, each 2.7 min on the sky, and 62 spectral channels per spatial element. An, as yet, unidentified feature was detected at approximately 3.52 micron in Comet Austin (on 1990 May 4, 5, and 6). The feature is possibly present in P/Brorsen-Metcalf (observed on 1989 August 23 and 25), as well. Comet Okazaki-Levy-Rudenko exhibited continuum emission only in this spectral region at the time of the observations (1989 November 14 and 16). The data are presented, and the relationship between the 3.52 micron feature and cometary activity (e.g., water production rate, visibility of the 3.4 micron emission feature) are discussed. The high resolution program probed comet Austin in the 4.8 micron region. These observations were used to search for emission lines comprising the (1-0) vibration-rotation band of the ground electronic state of CO. Retrieval of the lines allows a probe of the population distribution of levels J' = 1 through 4 of the excited (v' = 1) vibrational state within the ground electronic state of CO. Knowledge of this distribution can be used to constrain the rotational temperature. Preliminary analysis suggests the P3 line was present UT May 16 at roughly the 5 sigma level. Results concerning the existence of other lines, and physical conditions inferred therefrom are discussed.

Description: This paper describes a spectrometer/radiometer experiment to obtain infrared, visible, and ultraviolet measurements of Space Shuttle glow. The payload, Spacecraft Kinetic Infrared Test (SKIRT), is a cryogenic circular variable filter infrared spectrometer with a number of infrared, visible, and ultraviolet radiometers covering the spectral range of 0.2-5.4 microns and 9.9-10.3 microns. It will measure Shuttle glow as a function of mission elapsed time, orbiter attitude, temperature, and orbiter events such as thruster firings. The measured data should have sufficient spectral resolution and sensitivity to identify molecular species contributing to Shuttle glow emissions. SKIRT is manifested on STS-39.

Description: A demonstration-prototype CO2-laser heterodyne spectrometer operating at 9-12 microns and suitable for long-term space missions is described and illustrated with extensive diagrams, drawings, photographs, and graphs of test performance data. The spectrometer has total volume 0.63 cu m, mass 30 kg, and power requirement 60-70 W, compatible with miniature-class Space Shuttle experiment payload specifications. It comprises three modules: (1) an optical front end with reflecting optics, a 2-GHz BW HgCdTe photomixer, and a 0-2-GHz 40-dB RF preamplifier; (2) a local oscillator with an RF-excited waveguide CO2 laser, a 75-percent-efficiency RF amplifier, a stepper-driven grating mode selector, and an etalon stabilized for over 30,000 h of use; and (3) an RF-filter-bank spectral-line receiver with a 25-MHz RF channel, 1.6-GHz IF spectral coverage, onboard instrument control, a serial link to the host computer, and highly integrated design.