ISSN:
0377-0486
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
,
Physics
Notes:
Polycrystalline TlHSO4 was investigated by calorimetry (253-423 K) and by infrared (10-300 K) and Raman (10-420 K) spectroscopy. Two phase transitions are detected at 320 and 388 K. A complete assignment of the spectra of the room-temperature phase (III) is given and the spectroscopic results are consistent with infinite chains of hydrogen bonds. This structure appears disordered above 320 K (phase II). The high-temperature phase (I) presents the characteristic features of a plastic phase according to the spectroscopic manifestations of an increasing orientational disorder of sulphate ions. Above 360 K, a metastable phase (I′) showing a complex hydrogen-bonded framework is identified.
Additional Material:
7 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/jrs.1250250603
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