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  • 1
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 416-420 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 69 (1991), S. 7853-7861 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The correlation between the resistivity of TiB2 and the chemical vapor deposition parameters and subsequent annealing temperature have been studied. The films deposited from TiCl4 and B2H6 above 600 °C are found to be nearly stoichiometric TiB2 with a resistivity of 250 μΩ cm±20%, while those deposited below 600 °C are found to contain excess boron, and exhibit a higher resistivity. The resistivity of the films is observed to be independent of thickness in the thickness range from 15 to 550 nm. After high-temperature rapid thermal annealing ((approximately-greater-than)1000 °C), the resistivity is reduced to as low as 36 μΩ cm. The grain size in annealed films increases exponentially with temperature. The conductivity and the Hall mobility of the samples increase linearly with the grain size. The activation energy of grain growth, conductivity, and Hall mobility was found to be the same, 1.6–1.7 eV. From these results, it is evident that the carrier mobility of TiB2 is dominated by grain boundary scattering. The lower limit for resistivity of chemical vapor deposited TiB2 films is expected to be attainable only after annealing at temperatures approaching 1300 °C.
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 92 (1990), S. 3283-3291 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Rayleigh–Brillouin spectra of aqueous solutions of hydroxyl ammonium nitrate (HAN) and triethanol ammonium nitrate (TEAN) were studied at atmospheric pressure over a temperature range from 205 to 298 K. The hypersonic velocity and absorption coefficient of the phonons were calculated from the spectra as a function of temperature. The absorption due to viscosity and internal energy exchange through the relaxation mechanisms were considered. We find that both mechanisms are responsible for the absorption, but at the lower temperature, the one related to internal energy dominates. The free volume model was used to estimate the activation energy. This value is quite consistent with values calculated from the relaxation time. The effects of relaxation and the water concentration on mixtures of aqueous solutions of HAN and TEAN are also discussed.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    s.l. : American Chemical Society
    The @journal of organic chemistry 55 (1990), S. 4459-4461 
    ISSN: 1520-6904
    Source: ACS Legacy Archives
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 5
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 78-82 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: Neutron powder diffraction has been used to obtain the thermal parameters for the deuterium atoms and to confirm the crystal structure of acetonitrile-d3 at 4 K. Inelastic neutron scattering from both isotopic species is used to determine the energies of the first and second rotational levels of the methyl group. These four levels are reasonably reproduced by a threefold potential with V3=125 meV. The activation energy derived from this potential is in agreement with that previously obtained from the temperature dependence of T1 in proton magnetic resonance measurements.
    Type of Medium: Electronic Resource
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  • 6
    Electronic Resource
    Electronic Resource
    Oxford [u.a.] : International Union of Crystallography (IUCr)
    Acta crystallographica 46 (1990), S. 295-298 
    ISSN: 1600-5759
    Source: Crystallography Journals Online : IUCR Backfile Archive 1948-2001
    Topics: Chemistry and Pharmacology , Geosciences , Physics
    Type of Medium: Electronic Resource
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  • 7
    Electronic Resource
    Electronic Resource
    Springer
    Journal of thermal analysis and calorimetry 37 (1991), S. 2525-2539 
    ISSN: 1572-8943
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Description / Table of Contents: Zusammenfassung Es werden DSC-Untersuchungen an Hydroxylammoniumnitrat- (HAN) und Triethanolammoniumnitrat- (TEAN) Lösungen unterschiedlicher Konzentration dargestellt. Anhand der Ergebnisse wurden Phasendiagramme für diese Lösungen erstellt. Die gemessenen Schmelzpunkte dieser Flüssigkeiten wurden mit den theoretischen Berech nungen der Schmelzpunkterniedrigung verglichen. Die Schmelztemperaturen der HAN-Lösungen in einem bestimmten Konzentrationsbereich können viel besser unter Zuhilfenahme der Zwei-Elektrolyten-Annahme abgeschätzt werden. Das Phasendiagramm der TEAN-Lösungen belegt eine Instabilität in Übereinstimmung mit einer Phasenseparierung in dieser Flüssigkeit.
    Notes: Abstract We present Differential Scanning Calorimetry (DSC) results on Hydroxyl Ammonium Nitrate (HAN) solutions and Triethanol Ammonium Nitrate (TEAN) solutions with varying concentrations. These results are used to generate phase diagrams of these solutions. The results of the melting points of these liquids are compared with the theoretical calculations of the depression of melting points. The melting temperatures of the HAN solutions at some specified concentration range are predicted rather well using the two electrolyte assumption. The phase diagram of the TEAN solutions explains an instability with respect to phase separation of this liquid.
    Type of Medium: Electronic Resource
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  • 8
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 28 (1993), S. 3557-3563 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The textures of two different conical shaped liners, fabricated by the same forging processes from arc-cast and powder-sintered ingots, were investigated by using neutron-diffraction measurements and three-dimensional orientation-distribution-function (ODF) analysis. The major textures of both liners could be described by the (1 1 1) 〈uv w〉 and (1 0 0) 〈u v w 〉 type. The two liners had essentially identical texture at the 8 cm position (measured from the base of the cone) with strong sheet-type texture components, i.e. (1 1 1) 〈¯1 0 1〉, (1 1 1) 〈¯1 1 0〉 and (1 0 0) 〈0 1 1〉. However, the dominant textures at the 3 cm positions were 〈1 1 1〉 and 〈1 0 0〉 fibre textures with the fibre axes oriented parallel to the normal direction in both liners. A strong cube texture was observed at the 3 cm position of the arc-cast liner but it was not observed for the powder-sintered liner. The arc-cast liner had a generally higher degree of texture than the powder-sintered liner.
    Type of Medium: Electronic Resource
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  • 9
    Electronic Resource
    Electronic Resource
    Springer
    Journal of materials science 28 (1993), S. 3283-3290 
    ISSN: 1573-4803
    Source: Springer Online Journal Archives 1860-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: Abstract The orientation distributions of six tantalum samples, TaPA, TaG1, TaG2, TaQ2-S1, TaQ2-S2 and TaQ2-S4, were studied by neutron diffraction and ODF analysis. The TaPA specimen is a commercial tantalum sheet with an unknown fabrication history. The TaG1 and TaG2 were fabricated from a powder metallurgical ingot by uniaxial compression, and the TaQ2 type samples were fabricated from commercial stock by similar uniaxial forging. TaQ2-S1 is the section closest to the centre of the forged disc, S2 is the intermediate section, and S4 is the section adjacent to the periphery. The texture of TaPA consisted of many components, including {014}〈100〉, {111}〈¯321〉, {100}〈010〉, and [111]/[100] double-fibre textures with the fibre axes oriented parallel to the normal direction. The two TaG-type specimens were dominated by the [111]/[100] double-fibre texture, accompanied by a weak {100}〈010〉 cube texture. The three sections of TaQ2 had much higher degrees of texture than the TaG-type samples, with an extremely strong (111) peak, which consists of (111)〈11¯2〉, (111) 〈¯1¯12〉, and [111] fibre texture. The average pole density of the three equivalent orientations of (111)〈11¯2〉 was the strongest for the S1 with over 150 multiples of random distribution (mrd), and gradually decreased with increasing radial distance to about 100 mrd for the S4 section. On the other hand, the average intensity of (111)〈¯1¯12〉 type orientations was increased from about 40 mrd at S1 to about 100 mrd for the S4 section.
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  • 10
    Publication Date: 1993-06-01
    Print ISSN: 0022-2461
    Electronic ISSN: 1573-4803
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Published by Springer
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