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  • 1990-1994  (22)
  • 1
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 1699-1707 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The isochronal and isothermal annealing characteristics of acceptor-doped GaAs:Be grown at low substrate temperatures (300 °C) by molecular-beam epitaxy (LTMBE) have been studied. The Be was introduced in a range of concentrations from 1016 to 1019 cm−3. Electrical measurements of as-grown material up to the highest Be concentration of 1019 cm−3 show that no free holes are contributed to the valence band even though Raman spectroscopy of the Be local vibrational mode indicates that the majority of the Be impurities occupy substitutional sites. It is proposed that Be acceptors are rendered inactive by the high concentration of AsGa-related native donor defects present in LTMBE material. The concentration of AsGa-related defects in the neutral charge state was estimated from infrared absorption measurements to be as high as 3×1019 cm−3. A distinct annealing stage at 500 °C, similar to that found in irradiation-damaged and plastically deformed GaAs, marks a rapid decrease in the concentration of AsGa-related defects. A second annealing stage near 800 °C corresponds to the activation of Be acceptors. The presence of gallium vacancies VGa was investigated by slow positron annihilation. Results indicate an excess concentration of VGa in LTMBE layers over bulk-grown crystals. Analysis of isothermal annealing kinetics for the removal of AsGa-related defects gives an activation energy of 1.7±0.3 eV. The defect removal mechanism is modeled with VGa-assisted diffusion of AsGa to As precipitates.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 71 (1992), S. 2243-2248 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Amorphous carbon thin films were prepared at 30, 200, and 450 °C by magnetron sputtering of a graphite target. The surface structure and chemical bonding (sp2/sp3) of the carbon films were characterized by scanning tunneling microscopy (STM) and Raman spectroscopy. STM images show that graphite microcrystallites of 20–40 A(ring) in size are present at the surfaces of all the films and the number of the microcrystallites increases with increasing substrate temperature. The microcrystallites often contain structural defects. Raman measurements show that increasing the substrate temperature results in an increase in the sp2-bonded fraction of carbon atoms and a decrease in the microstructural defects. These results indicate that the microstructural changes are correlated with changes in the chemical bonding ratio (sp3/sp3) and no diamond microcrystallites are present in the amorphous carbon. A three-dimensional atomic structure of the graphite microcrystallites is discussed in terms of turbostratic graphite.
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  • 3
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 73 (1993), S. 2888-2894 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The combined electron and hole mobility of a single-crystal type IIa natural diamond and a polycrystalline diamond film deposited by chemical vapor deposition (CVD) were measured using transient photoconductivity as a function of excitation density (1013–1017 cm−3) and temperature (120–410 K). In natural diamond the temperature dependence suggests that the mobility is limited by phonon scattering at low free carrier densities, and by electron-hole scattering at high densities. The combined electron and hole phonon-limited mobility at room temperature is 3000 (±500) cm2/V s. In the CVD film, the mobility at room temperature was estimated to be 50 cm2/V s at low excitation densities. The temperature dependence of the mobility-lifetime product at low excitation densities is different from that of natural diamond, and suggests that charged center scattering, rather than acoustic phonon scattering, is the dominant effect. High densities of nitrogen and dislocations are known to be present in the natural diamond, and these appear to be the dominant recombination sites which limit the carrier lifetime. In the polycrystalline film a variety of structural defects and impurities are believed to exist, but it is unknown which of these dominates the transport and recombination properties.
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  • 4
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Tribological measurements have been performed on a series of carbon films deposited on untextured 95-mm magnetic disks by magnetron sputtering. Raman spectra and resistivity data of these films have been correlated to friction and wear performance. Tribochemical wear, as estimated by the rate of frictional buildup, is correlated to the G-band position in the Raman spectrum. Abrasive wear is best correlated to the I(D)/I(G) intensity ratio of the D and G bands, as well as to electrical resistivity. Interpretation of these data using structural models of amorphous carbon films is discussed.
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  • 5
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 7118-7123 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The effects of radiation damage and stoichiometry on the electrical activity of carbon implanted in GaAs are studied. Damage due to implantation of an ion heavier than C increases the number of C atoms which substitute for As (CAs). Creation of an amorphous layer by implantation and the subsequent solid phase epitaxy during annealing further enhances the concentration of CAs. However, the free carrier concentration does not increase linearly with increasing concentration of CAs due to compensating defects. Activation of implanted C is maximized by maintaining the stoichiometry of the substrate which reduces the number of compensating defects in the crystal. Under optimum conditions for carbon implanted at a dose of 5×1014 cm−2, the carbon acceptor activity can be increased from 2% to 65% of the total implanted carbon.
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  • 6
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 74 (1993), S. 1086-1095 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Electrical characteristics associated with radiation detection were measured on single-crystal natural type-IIa diamond using two techniques: charged particle-induced conductivity and time-resolved transient photoinduced conductivity. The two techniques complement each other: The charged particle-induced conductivity technique measures the product of the carrier mobility μ and lifetime τ throughout the bulk of the material while the transient photoconductivity technique measures the carrier mobility and lifetime independently at the first few micrometers of the material surface. For each technique, the μτ product was determined by integration of the respective signals. The collection distance that a free carrier drifts in an electric field was extracted by each technique. As a result, a direct comparison of bulk and surface electrical properties was performed. The data from these two techniques are in agreement, indicating no difference in the electrical properties between the bulk and the surface of the material. The collection distance continues to increase with field up to 25 kV/cm without saturation. Using the transient photoconductivity technique the carrier mobility was measured separately and compared with a simple electron-phonon scattering model. The general characteristics of carrier mobility, lifetime, and collection distance at low electric field appear to be adequately described by the model.
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  • 7
    Electronic Resource
    Electronic Resource
    [S.l.] : American Institute of Physics (AIP)
    Journal of Applied Physics 75 (1994), S. 1378-1383 
    ISSN: 1089-7550
    Source: AIP Digital Archive
    Topics: Physics
    Notes: The structural characteristics of ZnSe thin films grown by organometallic vapor phase epitaxy and implanted heavily with Cl ions (5×1015 and 1×1016/cm2) were investigated using ion beam techniques, x-ray diffraction, and Raman spectroscopy. We have found that although the as-implanted ZnSe layers were severely damaged, no amorphous layer was formed with an implant dose as high as 1×1016 Cl ions/cm2. Crystalline damage in the ZnSe layers was not fully removed even after annealing at 700 °C for 10 s. Ion channeling reveals that after annealing over 50% of the Cl atoms sit substitutionally in the lattice and they are preferentially located in the Se site. However, a significant fraction of the substitutional Cl are found to be slightly displaced from the normal Se sites. The projected displacement was found to be ≈0.2 A(ring). Electrical measurements and Raman spectroscopy results suggest that a large concentration of Zn vacancies (VZn) are present in the annealed samples. We believe that the Cl displacement and the low conductivity in these samples are due to the formation of (ClSe−VZn) complexes.
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  • 8
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 65 (1994), S. 1145-1147 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Raman spectra of carbon-doped GaAs and InP show two peaks which are characteristic of C clusters with sp2 bonding. The peaks are seen in C-implanted GaAs and InP following either rapid thermal annealing or furnace annealing. The peaks are also seen in heavily doped epilayers following furnace annealing. Various mechanisms for C precipitation are discussed. Experimental evidence suggests that the loss of the group V component at the surface during annealing may play a role in the precipitation of C.
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  • 9
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 63 (1993), S. 2756-2758 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: Using infrared and Raman spectroscopy, we have observed two local vibrational modes related to H bonded to N acceptors in ZnSe samples grown by metalorganic vapor phase epitaxy. We assign the new mode seen at 3194 cm−1 to a N—H stretching vibrational mode and tentatively assign the mode found at 783 cm−1 to a N—H wagging vibrational mode. Polarized Raman spectroscopy was used to determine that the symmetry of the defect complex is C3 v, which implies that the H atom is in either a bonding or antibonding position.
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  • 10
    Electronic Resource
    Electronic Resource
    Woodbury, NY : American Institute of Physics (AIP)
    Applied Physics Letters 59 (1991), S. 2386-2388 
    ISSN: 1077-3118
    Source: AIP Digital Archive
    Topics: Physics
    Notes: We report on the growth of high-quality diamond using a microwave plasma chemical vapor deposition (CVD) system in which the feed gas contains no hydrocarbons, but instead the source of carbon is a graphite piece which resides within the plasma volume. Results of experiments using this technique by itself and in combination with the normal methane feed gas method are described. The samples were analyzed by Raman spectroscopy and scanning electron microscopy. Diamond grown in this way was found to be particularly pure and of high crystallinity.
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