ISSN:
1436-2449
Source:
Springer Online Journal Archives 1860-2000
Topics:
Chemistry and Pharmacology
,
Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
,
Physics
Notes:
Abstract Some three years ago in a preliminary report from this laboratory we have proposed that the polymerization of isobutylene (IB) by the γ-tolyl-γ-valerolactone/BCl3 initiating system in CH3Cl or CH2Cl2 diluents at-30°C proceeds in a living manner by an unusual ring expansion mechanism and produces macrocyclic polyisobutylenes (PIBs) [1]. Extensive follow-up research confirmed the living nature of the polymerization, however, has failed to confirm the results of a key preliminary experiment upon which the proposition of macrocyclic polymer structure was based. Thus the results of a comparative hydrolysis/GPC experiment carried out with a relatively low molecular weight (Mn=5,400) PIB at -30°C under a blanket of N2 which gave a lower apparent molecular weight after hydrolysis than the original sample before hhydrolysis, could not be confirmed with higher molecular weight samples, i.e., with Mn=12,000, 17,000 and 30,000. As a consequence we wish to retract our earlier claim in regard to the synthesis of macrocyclic PIBs by certain lactone/BCl3 initiating systems but maintain that these polymerizations proceed in a living manner and yield asymmetric telechelic PIBs, e.g.,α-chloro-ε-carboxyl-PIBs [2].
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1007/BF00419972
Permalink
