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  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Planta 180 (1990), S. 154-165 
    ISSN: 1432-2048
    Keywords: Citrus ; Cuticle (composition, permeability) ; Lipid (soluble) ; Permeability (cuticle) ; Temperature and cuticle composition ; Wax (cuticle)
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract The constituents of the soluble cuticular lipids (SCL) of the leaf blades of Citrus aurantium L. were identified by gas chromatography-mass spectrometry and quantified. Major components were 1-alkanols (C24 to C40), n-alkyl esters (C36 to C56), n-alkanoic acids (C28 to C34), n-alkanes (C22 to C40) and triterpenones, while n-alkanals (C29 to C38), sterols, and alkyl benzenes (molecular weights 260, 274 and 288) made minor contributions. Leaf age and side significantly affected the quantitative composition of SCL. Increased day temperature during the development of leaves led to decreased amounts per unit area of n-alkanes, 1-alkanols, n-alkanoic acids and n-alkyl esters while increased night temperatures resulted in increased amounts of n-alkanes n-alkanoic acids and 1-alkanols. Relative humidity had no effect on the amounts or composition of SCL. The permeability of cuticular membranes to water (described in part I of this paper) and the composition of SCL were not related. A model for the molecular structure of the transport-limiting barrier of plant cuticles and for the transport of water across it is proposed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Springer
    International journal of thermophysics 14 (1993), S. 893-922 
    ISSN: 1572-9567
    Keywords: benzene ; carbon dioxide ; critical behavior ; data comparison ; diffusion coefficient ; diffusivity ; peak shape ; supercritical fluids ; Taylor dispersion ; toluene ; transport coefficients
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract This paper describes some of the experimental and theoretical problems encountered when the Taylor dispersion method is applied to the measurement of diffusion coefficients near gas-liquid critical points. We have used our own measurements of diffusion of benzene and toluene in supercritical carbon dioxide, along with measurements from several other sources, to illustrate some of the experimental challenges. Special attention is given to the peak shape. The intercomparisons are greatly simplified by comparing the experimental data as functions of density, rather than pressure. We find large and unexplained discrepancies between the various experimental sources. We discuss the theoretical predictions for the relationships between the diffusion coefficients and diffusivities obtained from Taylor dispersion and dynamic light scattering in fluids near critical points. We conclude that there is no strong reason to press for Taylor dispersion measurements near the gas-liquid critical point of the carrier gas.
    Type of Medium: Electronic Resource
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