ISSN:
0009-2940
Keywords:
1-Thia-3-azoniabutatriene salts
;
2-Azoniaallene salts
;
1,3-Dipolar cycloadditions
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1-Thia-3-azoniabutatriene salts 1 react with alcohols, carbonyl compounds, diazo alkanes, nitrile oxides, nitrones, enamines, and 1,3-butadienes in all cases at the C=S double bond to yield new types of 2-azoniaallene salts (3, 9a, b, 13a, b, 18, 22) and other imines (2, 20). An X-ray diffraction analysis for 9b, the reaction product of 1b with 9-diazofluorene, confirms the proposed constitution.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241124
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