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  • Fluoride ion  (1)
  • Parameter estimation  (1)
  • 1990-1994  (2)
  • 1
    ISSN: 1572-8927
    Schlagwort(e): Fluoride ion ; solvation ; transfer free energy ; acidity parameters
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Linear free energy relationships between the free energy of transfer of fluoride ion from water to other solvents or solvent mixtures and each of several parameters describing the acidity of the solvent were found. The correlation is about of the same quality for the A parameter of Swain or the acceptor number, AN, and almost as good for the α parameter of Taft. The correlation was somewhat poorer with the E T (30) parameter.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    Digitale Medien
    Digitale Medien
    Springer
    Annals of biomedical engineering 21 (1993), S. 221-236 
    ISSN: 1573-9686
    Schlagwort(e): System identification ; Total artificial heart ; Parameter estimation ; Systemic arterial parameters
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Medizin , Technik allgemein
    Notizen: Abstract A new algorithm for estimating systemic arterial parameters from systolic pressure and flow measurements at the root of the aorta is developed and tested through a systems identification approach. The resulting procedure has direct application to a total artificial heart (TAH) control system currently under development. Identification models, representing the systemic arterial system, are developed from existing work in the area of cardiovascular modeling. The resistive and compliance components of these models are physically significant, representing overall hydraulic properties of the systemic arterial system. A unique method of parameterizing the identification models is designed which operates on the basis of aortic pressure and flow measurements taken exclusively during systole. The estimator is a modified recursive least squares algorithm which utilizes covariance modification to track time-varying parameters and a dead-zone to improve the robustness. Performance of the estimation algorithm was tested on data generated by a higher-order distributed model of the systemic arterial bed using normal canine parameters. Results from model-to-model experiments verify the consistency of the estimates and the ability of the estimator to converge quickly and track dynamically varying parameters.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
    BibTip Andere fanden auch interessant ...
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