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  • Gas chromatography  (3)
  • SOLAR PHYSICS  (2)
  • FABRICATION TECHNOLOGY
  • SPACE RADIATION
  • 1990-1994  (5)
  • 1
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Stationary phase characterization ; Principal component analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary In this study, several new stationary phases were characterized by principal component analysis. Fourteen new stationary phases, including substituted phenyl and oligoethyleneoxide functionalities on polysiloxane polymers, were tested and compared to three well known stationary phases. The main features of these phases were studied using a series of test solutes of varying chemical characteristics representing the data set for principal component analysis. Two principal compounds were found to account for 99.20% of the variance (the first accounted for 94.96% and the second for 4.24%). The data were represented as a two-dimensional map for visual representation of the characteristics of these stationary phases. The first principal component represented a selectivity based on polarity (r2=0.998), while the second showed Lewis acid-base characteristics of the phases. Polarizable and amphoteric characteristics of these phases also became evident using this evaluation method.
    Type of Medium: Electronic Resource
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  • 2
    ISSN: 1612-1112
    Keywords: Supercritical fluid chromatography ; Gas chromatography ; High speed analysis ; Thermal desorption ; Two dimensional analysis
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary A two-dimensional supercritical fluid-gas chromatography system was constructed and evaluated. A 50-μm i.d. capillary column coated with a 50 % cyanopropyl polysilixane stationary phase was used as the firstdimensional column. Group-type separations of polycyclic aromatic hydrocarbons, based on the number of aromatic rings, were achieved using this column under SFC conditions. A 25-μm i.d. liquid crystal column was used as the second-dimensional column under GC conditions. The effluent from the first column (SFC) was received continuously by the second column (GC) through a thermal desorption modulator. The thermal desorption modulator (prepared at the head of the second column) generated a series of concentration pulses from the first column effluent. These concentration pulses served as injections to the second column, and were developed into a corresponding series of high-speed chromatograms. Grouptype sample bands from the first column were separated into individual components on the second column. All sample substances passed through both columns to generate two sets of retention data, which could be used for more accurate compound identification.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Springer
    Chromatographia 33 (1992), S. 507-513 
    ISSN: 1612-1112
    Keywords: Gas chromatography ; Supercritical fluid chromatography ; Supercritical carbon dioxide ; Sulfur chemiluminescence detection
    Source: Springer Online Journal Archives 1860-2000
    Topics: Chemistry and Pharmacology
    Notes: Summary Sulfur chemiluminescence detection (SCD) for the determination of sulfur-containing compounds in gas chromatography (GC) and supercritical fluid chromatography (SFC) is described. The detector is based on the chemiluminescence reaction of ozone with sulfur monoxide which is produced in an H2/O2 reducing flame from sulfur-containing analytes. High selectivity over nonsulfur-containing species has been achieved for a number of mercaptans and sulfur-containing polycyclic aromatic hydrocarbons. Minimum detectable quantities of 23 and 26 pg S (S/N=3) for dibenzothiophene and benzo[b]naphtho[1,2-d]thiophene, respectively, have been obtained using the SFC/SCD system. It was found that connecting a buffer volume flask to the vent of the vacuum pump that draws the effluents and ozone gas into the chemiluminescence reaction chamber, increases the sensitivity of the SCD.
    Type of Medium: Electronic Resource
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  • 4
    Publication Date: 2019-08-28
    Description: Five pressure-balanced structures, each with a scale of the order of a few hundredths of an astonomical unit (AU), were identified in two merged interaction regions (MIRs) near 35 AU in the Voyager 2 plasma and magnetic field data. They include a tangential discountinuity, simple and complex magnetic holes, slow correlated variations among the plasma and magnetic field parameters, and complex uncorrelated variations among the parameters. The changes in the magnetic pressure in these events are balanced by changes in the pressure of interstellar pickup protons. Thus the pickup protons probably play a major role in the dynamics of the MIRs. The solar wind proton and electron pressures are relatively unimportant in the MIRs at 35 AU and beyond. The region near 35 AU is transition region: the Sun is the source of the magnetic field, but the interstellar medium in source of pickups protons. Relative to the solar wind proton guyroadius, the thicknesses of the discontinuities and simple magnetic holes observed near 35 AU are at least an order of magnitude greater than those observed at 1 AU. However, the thicknesses of the tangential discontinuity and simple magnetic holes observed near 35 AU (in units of the pickup proton Larmor radius) are comparable to those observed at 1 AU (in units of the solar wind proton gyroradius). Thus the gyroradius of interstellar pickup protons controls the thickness of current sheets near 35 AU. We determine the interstellar pickup proton pressure in the PBSs. Using a model for the pickup proton temperature, we estimate that the average interstellar pickup proton pressure, temperature, and density in the MIRs at 35 AU are (0.53 +/- 0.14) x 10(exp -12) erg/cu cm, (5.8 +/- 0.4) x 10(exp 6) K and (7 +/- 2) x 10(exp -4)/cu cm.
    Keywords: SOLAR PHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; A11; p. 21,511-21,524
    Format: text
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  • 5
    Publication Date: 2019-08-28
    Description: Evidence is presented for focused transport of energetic particles along magnetic field lines draped around a coronal mass ejection. This evidence was obtained with the University of Maryland/Max-Planck-Institute experiment on the ISEE-3 spacecraft during the decay phase of the June 6, 1979, solar particle event. During the early portion of the decay phase of this event, interplanetary magnetic field lines were apparently draped around a coronal mass ejection, leading to a small focusing length on the western flank where ISEE 3 was located. A period of very slow decrease of particle intensity was observed, along with large sunward anisotropy in the solar wind frame, which is inconsistent with predictions of the standard Fokker-Planck equation models for diffusive transport. It was found possible to fit the observations, assuming that focused transport dominates and that the particle pitch angle scattering is isotropic.
    Keywords: SOLAR PHYSICS
    Type: Journal of Geophysical Research (ISSN 0148-0227); 97; 1597-160
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