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  • Chemistry  (3)
  • United States
  • 1990-1994  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Particle and Particle Systems Characterization 10 (1993), S. 266-270 
    ISSN: 0934-0866
    Keywords: Chemistry ; Industrial Chemistry and Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: On-line characterization of powder and droplets during gas atomization of molten metals and alloys offers extensive opportunities for real-time process monitoring and control. The capability to make on-line measurements can significantly reduce tedious and costly powder classification, which, currently, is always carried out subsequent to the atomization process. Two laser-based particle sizing instruments, the EPCS (ensemble instrument) and PCSV (single particle instrument), were used during gas atomization of zinc with a double Coanda nozzle configuration. The laser instruments were positioned in the duct leading from the bottom of the atomization tower to the powder collection cyclone. The effect of gas to metal ratio on particle size was studied by varying the atomization gas pressure from 0.69 MPa to 1.03 MPa. Air was used as the atomizing gas for some of the 0.69 MPa runs, while nitrogen was used for all of the higher-pressure runs. Experimental apparatus and procedures for atomization and on-line powder sizing with the EPCS and PCSV are described. EPCS and PCSV measurements, which were compared with standard sieve analyses, indicate that the ensemble instrument is a good candidate for on-line process monitoring and control.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 28 (1990), S. 275-276 
    ISSN: 0749-1581
    Keywords: 13C NMR ; 1J(CH) ; 2-Nitrocyclohexanones ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The 13C NMR spectra of 22 α-nitrocyclohexanones were recorded and fully assigned. The one-bond C—H coupling constants for the nitromethine resonances of these compounds were also obtained and tabulated.
    Additional Material: 1 Tab.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 32 (1994), S. 259-262 
    ISSN: 0749-1581
    Keywords: 77Se NMR ; 13C NMR ; 1H NMR ; Phenylselenenylazidocyclohexanes ; Phenylselenenylchlorocyclohexanes ; 1-Phenylselenenylmethylcyclohexene conformation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The 77Se, 13C and 1H NMR spectra of the products of phenylselenenyl azide and chloride addition to methylenecyclohexane and cyclohexene are presented. Scalar couplings between 77Se and 1H/13C allowed the absolute assignment of the regioisomers in the 1H and 13C spectra. Low-temperature 77Se NMR was used to determine the conformer ratios for 1-azidomethyl- and 1-chloromethyl-1-phenylselenenylcyclohexane anti-Markovnikov addition products.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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