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  • 1
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 15 (1992), S. 1149-1170 
    ISSN: 0271-2091
    Keywords: Coastal upwelling ; Turbulence energy ; Exchange coefficient ; Roughness length ; Co-ordinate transformation ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A three-dimensional numerical model has been applied to study the impact of freshwater discharge from a river on the coastal circulation in the western Bay of Bengal. The basic dynamical framework of the model follows closely that described by Johns et al.1 for the simulation of coastal upwelling off the east coast of India. Using this model, experiments have been performed to investigate the impact of the freshwater discharge at the location of Godavari river along the east coast of India. A comparison of the model results, with and without the inclusion of river discharge, shows that the river discharge into the western Bay of Bengal suppresses the upwelling near the river mouth. Though there are no detailed observations on the flow structure near the mouth of the Godavari river, the computed results are in qualitative agreement with the observations documented by Rao and Jayaraman2 and Rao,3 who have shown that during monsoon period the upwelling off Godavari estuary is suppressed.
    Additional Material: 12 Ill.
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 29-38 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A kinetic model is developed for the drying of solids in fluidized beds, assuming a falling rate period following a constant rate period. Experimental data obtained using batch and continuous single and spiral fluidized beds are satisfactorily matched with the assumed drying kinetics and the residence time distribution of solids appropriate for the type of dryer.
    Additional Material: 13 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 1825-1834 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Unsteady axial mixing due to addition of a batch of sodium chloride solution at the top of a water-filled tube (2.63 cm i.d.) has been studied by measuring the developing concentration profile and the advancing front with dye added to the brine. Data have also been obtained with added baffle plates, with the use of a viscous aqueous solution, and in smaller diameter (1.48, 1.91 cm) tubes. Results can be approximately correlated by means of a model based on unsteady one-dimensional turbulent dispersion. Laminar flow affects the behavior of the advancing front at which the salt concentration is lowest.
    Additional Material: 12 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 1249-1254 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A mathematical model is developed to describe steady-state nonequilibrium surface diffusion of an adsorbing gas through an energetically homogeneous porous medium by assuming that the adsorption isotherm is linear and that the gas-surface mass transfer can be described by the linear driving force model. Analytical solutions for the model are reported. It is found that the conventional assumption of local thermodynamic equilibrium between the gas and surface phases within the porous medium can seriously underestimate the surface diffusivity when the mass transfer rate is finite. Also, the length of the porous medium becomes a critical variable in that case.Meaningful estimation of surface diffusivity also requires that the gas phase diffusivity through the porous medium be accurately known. The estimated surface diffusivity is model dependent when local thermodynamic equilibrium is not established instantaneously. Modeling surface diffusion can be very complex when the surface is energetically heterogeneous.
    Additional Material: 5 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 38 (1992), S. 811-820 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A framework is developed to describe kinetics and column dynamics of ad(de)sorption from bulk liquid mixtures using surface excess as the variable to quantify the extent of adsorption. It is found that the transient rate of change of surface excess with time from a multicomponent liquid mixture can be expressed in terms of a surface excess linear-driving-force model. A local-equilibrium model can be developed to describe the column dynamics of ad(de)sorption from liquid mixtures. Both self-sharpening and proportionate pattern mass-transfer zones can be formed depending on the shape of the surface-excess isotherm and the selectivity of adsorption. Analysis of column dynamics for liquid mixture adsorption can be carried out analogous to that for adsorption from gas mixtures, when a constant pattern mass-transfer zone is formed. The length of the mass-transfer zone and the composition-time column effluent profile can also be derived analytically for such a case. Experimental kinetics and column dynamics data for ad(de)sorption of ethanol-water mixtures on a large-pore activated carbon are analyzed using these models.
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 249-261 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: In this article, we present a model to describe sorption kinetics of gaseous adsorbates onto bidispersed heterogeneous microporous particles. This model describes adsorption and desorption of gaseous adsorbates with allowance for the energy distribution of adsorption site for both equilibrium isotherm and diffusion of the adsorbed species. The adsorbed species of all energy level diffuse in two directions inside the particle. One direction is the direction along the particle coordinate while the other is the direction perpendicular to the particle coordinate (that is, the direction into the grain of the solid). This model is more fundamental than models previously proposed by Do and coworkers. Effects of energy distribution on the adsorption and desorption dynamics are investigated. Extensive experimental analysis of adsorption and desorption dynamics of ethane and propane onto Ajax activated carbon are carried out to validate this theory.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 37 (1991), S. 1019-1026 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Axial dispersion coefficients have been measured in single-phase flow conditions in a 5.08-cm-dia. reciprocating plate extraction column. The measurements were done under steady-state conditions by analyzing temperature profiles (for hot and cold water mixing) and concentration profiles (for mixing of water and salt solutions). The results confirm previous published data of Holmes et al. (1991) in showing that axial dispersion is increased strongly in the unstable situation, where liquid density increases with height. The earlier work is extended to the condition where buoyant energy dissipation is exceeded by mechanical energy dissipation by four orders of magnitude. Even in this case, axial mixing is increased significantly by density gradient-induced instability. Results have been correlated by a simple equation based on a mixing length model.
    Additional Material: 10 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 39 (1993), S. 1870-1884 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: A numerical study of the bulk hydraircooling of spherical food products is performed using the technique of spraying chilled water to form a thin film over the food products while blowing cold unsaturated air in the countercurrent or cocurrent direction. This precooling process is found to combine the advantages of hydro-and air cooling.Governing equations describing the simultaneous heat and mass transfer occurring in the hydraircooling process for both counterflow and parallel-flow arrangements are solved using finite-difference numerical methods. A parametric study is performed to determine the effect of important processing parameters on the process time. It is generally observed that higher quantities of spray water, air-mass flow rate and product thermal conductivity, as well as lower values of water temperature will result in faster rates of cooling. For the same operating conditions, parallel-flow arrangement leads to higher plant capacities.
    Additional Material: 18 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 47 (1993), S. 437-448 
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: In this paper, we present a symmetrical and adiabatic reaction path for hydrogen transfer from methane by methyl by an ab initio method using the 6-31G** basis set with the MP2 corrections for UHF/6-31G** optimized geometries. The theoretical barrier is fitted with the symmetric Eckart function. We, then, take thermal averages of the rate constant (k) considering the discrete nature of the C-H oscillators and the continuous character of the various low-frequency modes of the composite system. Finally, we present a linear relation between log k and temperature. It is shown that this relation gives a good description of the kinetic results of both thermal and photochemical H-transfer reactions in the region of low temperatures. © 1993 John Wiley & Sons, Inc.
    Additional Material: 4 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 36 (1993), S. 997-1012 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The paper presents the results of investigations conducted to evaluate the added mass to represent fluid-structure interaction effects in vibration/dynamic analysis of floating bodies such as ship hulls. While the structural plating is idealized by 9-noded plate/shell finite elements, the fluid domain is modelled by 20-noded/21-noded 3-D finite elements in the investigations conducted. A new 8-noded element has been developed to model the interface between the structure and the fluid. An efficient computational methodology has been used for computation of added mass. The finite element models are validated by comparing the results with those given by analytical solution for a submerged sphere. The efficacy of the finite element model is demonstrated through convergence of the results obtained for a floating barge problem. A better convergence rate and distribution of added mass in three orthogonal directions have been obtained.
    Additional Material: 8 Ill.
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