ALBERT

Description: Results are presented on a ground-based search for fluorescent emission from CH4 at 3.3 microns in a newly discovered long-period comet, Comet Levy (1990c). It was found that the upper limit to the CH4 abundance in Comet Levy is similar to the Comet Halley CH4 abundance estimated from lower resolution IR spectra by Kawara et al. (1988). The Comet Levy CH4 abundance is significantly lower than the abundance derived by Larson et al. (1989) from a possible detection of CH4 in Comet Wilson.

Description: Ultraviolet (UV) spectra of comet P/Hartley 2 (1991 XV) taken with the Faint Object Spectrograph (FOS) on the Hubble Space Telescope (HST) in 1991 September reveal several bands of the Cameron system of CO (a 3 Pi-X 1 Sigma). These band are most likely due to 'prompt' emission from CO2 and, thus, provide a direct tracer of the CO2 abundance in the nucleus. Photodissociative excitation of CO2 is probably the largest contributor to the Cameron band emission, but significant contributions from electron impact excitation of CO, electron impact dissociation of CO2, and dissociative recombination of CO2(+), are also possible. Using our estimate that photodissociative excitation is responsible for approximately 60% of the total excitation of the Cameron system, we derive Q(sub CO2) approximately 2.6 x 10(exp 27) molecules/s, which implies CO2/H20 approximately 4%. If all of the Cameron band emission is due to photodissociative excitation, then CO2/H2O = 7 +/- 2%. For the largest possible contributions from the other excitation mechanisms considered, the CO2 abundance could be as a small as aproximately 2-3%. We did not detect CO Fourth Positive Group emission in our data and derive an upper limit of CO/H2O less than or equal to 1% (3 sigma) for CO coming directly from the nucleus. Comparison of the relative CO2 and CO abundances in P/Hartley 2 to those in P/Halley (CO2/H2O approximately 3%-4%, CO/H20 approximately 4% for the nucleus source) indicates that selective devolatilization of the nucleus may have occurred for P/Hartley 2. A relatively large CO2/CO ratio (i.e., approximately greater than 1) seems to be a common property of cometary nuclei. Since gas phase chemistry, in either the solar nebula or the interstellar medium (ISM), appears incapable of producing large relative CO2 abundances, the CO2 in cometary nuclei is probably produced either by UV and/or cosmic ray irradiation of ISM grains prior to the formation of the Solar System, or by condensation fractionation in the solar nebula.

Description: A comparison of images of Titan obtained by the HST in August, 1990 with Voyager 1 and 2 images respectively obtained 10 and 9 years earlier has indicated a reversal of the seasonal hemispheric brightness asymmetry near 440 and 550 nm wavelengths; the northern hemisphere is in the more recent observations the brighter of the two, by about 10 percent. Titan's albedo pattern is therefore adequately explained by a seasonal model.

Description: The wealth of information on cometary physics provided by high-resolution spectroscopy of the IR water transitions is discussed. Specifically, the absolute line intensities and spatial brightness profiles are used to determine water production rates and lifetimes; the relative line intensities and spatial brightness profiles are used to determine water production rates and lifetimes; the relative line intensities probe the kinetic temperature profile in the coma; the line widths and line positions shed light on the coma outflow dynamics; and the temporal variability in the lines provides information on the structure of the nucleus. These observations also make it possible to determine the water ortho-to-para ratio, which may elucidate the origin and/or evolution of cometary nuclei. Recent advances in IR instrumentation promise to extend sensitivities for parent molecule searches to relative abundances well below 1 percent, especially if cooled, earth-orbiting facilities are available.