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  • Articles  (145)
  • Wiley-Blackwell  (145)
  • Physics  (137)
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  • Articles  (145)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 58 (1995), S. 1585-1592 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: Polycyclotrimerization of a flexible aromatic dicyanate with a Schiff base structure was studied by means of differential scanning calorimetry (DSC). The study on dynamic DSC evaluated an apparent activation energy (Ea) of 75.8 kJ/mol and autocatalytic first-order kinetics with rate expression Af(α) = 1.96 X 105 (1 + 4.39 α) (1 - α) min-1. The kinetic feature can be explained by a proposed mechanism consisting of hydroxyl-catalyzed and autocatalytic paths. The lower value of Ea compared with other aromatic dicyanates is due to the electron-withdrawing linkage of the inherent imine ( - CH=N) structure. The kinetic feature is affected by the content of the residual impurities (e.g., phenols or absorbed water) in the corresponding sample. © 1995 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 2
    ISSN: 0894-3230
    Keywords: Organic Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Peroxidation of linoleic acid was initiated by azobis(isobutyronitrile) in tert-butyl alcohol and inhibited by α-tocopherol, β-carotene and retinal, either alone or in combination. Significant antioxidant synergism and a novel mutual protection of α-tocopherol and β-carotene were found and the possible involvement of retinal in the process is discussed.
    Additional Material: 5 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Stamford, Conn. [u.a.] : Wiley-Blackwell
    Polymer Engineering and Science 34 (1994), S. 986-994 
    ISSN: 0032-3888
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: The flow analysis network (FAN) method was modified to analyze the flow of poly(methyl methacrylate) (PMMA) in a model counter-rotating nonintermeshing screw extruder. The numerical prediction of the pressure profiles was compared with the experimental results. Flow patterns in the screw elements of the model counter-rotating nonintermeshing twin screw extruder were also predicted. A new flow path method was developed to calculate the residence time distribution. This result will be applied to analyze the flow during the reaction in the model twin screw extruder.
    Additional Material: 21 Ill.
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  • 4
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Electric properties of suspension chlorinated polyethylenes (chlorine content about 73%) are investigated at the frequency of 5 MHz, within the temperature range from 20 to 80°C. The observed relaxations are dependent on the chemical structure of the polymer.In addition, dynamic mechanical properties are studied within a temperature range of -100 to +190°C. No parallelism is noticed between electrical and mechanical properties for this rigid-chain polymer.
    Notes: Les propriétés électriques de polyéthylènes chlorés en suspension (taux de chlore, 73% environ) ont été étudiées à la fréquence de 5 MHz dans une gamme de température de 20 à 80°C. Les relaxations observées varient avec la structure chimique du polymère.Les propriétés mécaniques dynamiques ont été étudiées en basse fréquence dans une gamme de température de -100 à +190°C. On n'observe pas de parallélisme entre propriétés électriques et mécaniques pour ces polymères dont les chaînes sont très rigides.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 192 (1991), S. 301-307 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Rapid scanning Fourier transform infra-red spectroscopy was used to follow the changes in the population of trans conformers and in the infra-red dichroic functions of the bands characterizing the trans (T) and gauche (G) conformers and the chains in the amorphous regions during stretching of a solution-cast amorphous poly(ethylene terephthalate) (PET) film A in the glassy state (67°C) and in the rubbery state (88°C). Stretching at 67°C showed a yield stress peak followed by strain softening in the stress-strain curve. The population of trans conformers in the amorphous and crystalline regions, Ta + Tc, decreased in the pre-yielding region and then increased continuously after yielding. The T conformers formed during post-yield stretching showed high orientation, while the G conformers remained in low degree of orientation. Stretching at 88°C showed no pronounced yield stress peak in the stress-strain curve, and the population of T conformers did not change until the beginning strain-induced crystallization. A solvent-cast PET film annealed at 67°C for 24 h, the film N, showed a sharp and high yield stress peak in the stress-strain curve, and strain-induced crystallization occurred at lower draw ratio as compared to the film A. The film A showed a non-equilibrium high population of Ta conformers, part of which reverted to G conformers during sub-Tg annealing.
    Additional Material: 4 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester, West Sussex : Wiley-Blackwell
    Mathematical Methods in the Applied Sciences 21 (1998), S. 25-42 
    ISSN: 0170-4214
    Keywords: Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics
    Notes: Considered is the rotation of a robot arm or rod in a horizontal plane about an axis through the arm's fixed end and driven by a motor whose torque is controlled. The model was derived and investigated computationally by Sakawa and co-authors in [7] for the case that the arm is described as a homogeneous Euler beam. The resulting equation of motion is a partial differential equation of the type of a wave equation which is linear with respect to the state, if the control is fixed, and non-linear with respect to the control.Considered is the problem of steering the beam, within a given time interval, from the position of rest for the angle zero into the position of rest under a certain given angle.At first we show that, for every L2-control, there is exactly one (weak) solution of the initial boundary value problem which describes the vibrating system without the end condition.Then we show that the problem of controllability is equivalent to a non-linear moment problem. This, however, is not exactly solvable. Therefore, an iteration method is developed which leads to an approximate solution of sufficient accuracy in two steps. This method is numerically implemented and demonstrated by an example. © 1998 by B. G. Teubner Stuttgart-John Wiley & Sons Ltd.
    Additional Material: 10 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Communications in Numerical Methods in Engineering 13 (1997), S. 285-299 
    ISSN: 1069-8299
    Keywords: error estimates ; remeshing strategies ; finite elements ; adaptive analysis ; elasto-plastic analysis ; Engineering ; Numerical Methods and Modeling
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The major difficulty in applying the finite element method to practical problems is the design of a suitable mesh and the assessment of discretization errors. To overcome this difficulty considerable effort has been made in developing adaptive finite element methods, but most of the work has been limited to linear problems. In this paper, fundamental concepts related to error estimates and mesh refinement strategies for non-linear problems are addressed. A simple, but reliable, path-dependent error estimator is proposed. Based on the errors estimated by the present method, a mesh refinement strategy is also suggested. Numerical examples of two ideal plasticity plane stress problems are shown. The non-linear plasticity model is based on an incremental theory using the von Mises yield criterion. © 1997 by John Wiley & Sons, Ltd.
    Additional Material: 11 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 160 (1972), S. 251-258 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Grenzflächenpolykondensation von Silanen mit Hydrazinen wurden Polymere der Struktur I hergestellt. Dabei kam ein modifiziertes wasserfreies Lösungsmittelsystem aus Acetonitril und Kohlenwasserstoffen zur Anwendung.Die Produkte haben nur niedrige Molekulargewichte. Eine Zuordnung der IR-Banden wird gegeben.
    Notes: Polymers of the form below were prepared by the interfacial method via the condensation of silanes with hydrazines employing a modified nonaqueous system using acetonitrile and liquid hydrocarbons. IR frequency band assignments are given. The products are oligomeric.
    Additional Material: 1 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 152 (1972), S. 43-47 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Description / Table of Contents: Durch Umsetzung von Polyacrylnitril mit Hydroxylamin und dann mit Organometallhalogeniden von Sn, Ge oder Si wurden modifizierte Polymere erhalten, die wahrscheinlich folgende Struktur aufweisen: Mit Cl2MR2 entstehen vernetzte Produkte. Die neuen Polymeren werden kurz charakterisiert.
    Notes: Poly(acrylonitrile) was modified to give products of the form below via reaction with hydroxylamine and subsequently with group IV organometallic reactants: The products obtained with Cl2MR2 are crosslinked. Properties of the new polymers are briefly characterized.
    Additional Material: 1 Tab.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 34 (1992), S. 171-177 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A universal method which can be used to generalize thin plate elements to thick ones without adding any extra degree of freedom (DOF) is presented in this paper. To illustrate this method, a rectangular moderately thick plate element with 12 DOF is constructed on the basis of the well known thin plate ACM element. The element can be used in the analysis of both thin and thick plates. Shear locking is avoided.
    Additional Material: 1 Ill.
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