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  • Chemical Engineering  (3)
  • Analytical Chemistry and Spectroscopy  (1)
  • Wiley-Blackwell  (4)
  • Hindawi
  • 1990-1994  (4)
  • 1
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 40 (1994), S. 2055-2059 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Hoboken, NJ : Wiley-Blackwell
    AIChE Journal 36 (1990), S. 746-752 
    ISSN: 0001-1541
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: Competitive liquid-phase hydrodesulfurization of thiophene and hydrogenation of cyclohexene on a monolithic CoMo/γ-Al2O3 catalyst were studied. The flow pattern in the monolithic catalyst reactor was segmented gas-liquid flow (slug flow). The hydrogen pressure and the temperature were varied between 30-40 bar and 509-523 K, respectively. The experimental data are consistent with rate expressions of the Langmuir-Hinshelwood type where the reactions proceed on two different types of active sites. This kinetic model is based on hydrogenation of the thiophene ring prior to sulfur elimination.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 3
    ISSN: 1040-7685
    Keywords: fullerene-linked polymer ; fullerene-linked silica ; synthesis ; stationary phases ; microcolumns ; polycyclic aromatics ; polychlorinated biphenyls ; environmental contaminants ; liquid chromatography ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Fullerenes (C60 and C70) linked to small silica or polymer particles provide novel chromatographic stationary phases with electron donor/acceptor surface interactions that may parallel those of aromatic carbons. Separations of fullerenes and aromatic compounds frequently encountered as environmental contaminants were investigated using LC microcolumns containing either particles prepared from BrHC60 linked to amino-silica (Spherisorb-NH2, Phenomenex) or porous polymers containing ca. 12% fullerene by weight. The polystyrene divinylbenzene (PSDVB)-C60/70H column had greater capacity (k') than the Si—NH—C60/70H column. Toluene and polycyclic aromatic hydrocarbons (PAHs), naphthalene, anthracene, pyrene, and perylene, were retained in the order of increasing ring number; nitro-substituents increased retention; and chlorinated-dibenzo-p-dioxins and -dibenzofurans were more strongly retained than their parent compounds. PCB congeners with no chlorine in the ortho, ortho'-positions are co-planar and are strongly retained; for these isomers, retention increased with higher chlorination. We demonstrate that surface-linked fullerenes can also accommodate further chemical modification through the addition of 2-(4-nitrophenyl)ethyl or -NH—CH2CH2NH2 moieties to yield altered electron donor/acceptor affinity. Separations appear to be derived primarily from aromatic electron induced dipole-dipole or electron-pair donor or acceptor interactions (charge transfer complexes). Except for the fullerenes, surface interactions with compounds are largely suppressed with methylene chloride as the mobile phase.
    Additional Material: 12 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Brookfield, Conn. : Wiley-Blackwell
    Journal of Vinyl and Additive Technology 15 (1993), S. 17-21 
    ISSN: 0193-7197
    Keywords: Chemistry ; Chemical Engineering
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Process Engineering, Biotechnology, Nutrition Technology
    Notes: This study seeks to substitute fumed silica for chlorinated polyethylene (CPE) within a rigid PVC formulation intended for profile extrusion such as doors and window frames. The effect of fumed silica on both mechanical (tensile and impact) and thermal (Vicat point, HDT, and linear thermal expansion coefficient) properties were investigated. Five rigid PVC formulations were prepared, including a reference one (F1), then F1 with CPE, F1 with untreated silica, F1 with heat treated silica, and finally F1 with dried silica and a coupling agent. The effect of CPE on mechanical properties was very modest. On the other hand, CPE showed its inefficiency, in that HDT and Vicat point were decreased. Heat treated silica showed the greatest improvement in both mechanical and thermal properties. Untreated silica showed a small effect on both properties. Finally, the incorporation of coupling agent gave considerable improvement in both mechanical and thermal properties.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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