ISSN:
0009-2940
Keywords:
Electrochemistry
;
1-Nitroalkenes, reduction of
;
Oximes
;
Amines
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
1-Nitroalkenes are reduced in high yields at -0.3 to -0.5 V (vs. SCE) at a mercury or graphite cathode to oximes. At higher cathodic reduction potentials (- 1.1 V) primary amines are selectively obtained in fair yields. Nitroalkadienes are selectively reduced at the double bond conjugated with the nitro group to either the oxime or amine.
Additional Material:
4 Tab.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911241024
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