ISSN:
0894-3230
Schlagwort(e):
Organic Chemistry
;
Physical Chemistry
Quelle:
Wiley InterScience Backfile Collection 1832-2000
Thema:
Chemie und Pharmazie
,
Physik
Notizen:
For a number of chiral α,β-unsaturated carbonyl compounds, cyclohexanone and cyclohexenone derivatives, existing essentially in the form of single molecular conformation, the correlation dependences were established between the values of the calculated dissymmetry functions (DF) with respect to atomic masses and atom refractions, and the induction effectiveness of helical ordering in the nematic mesophase (twisting power). Such correlative dependencies, as the examples show, allow one to predict safely enough the twisting power of new substances with the ‘fixed’ molecular conformation. Types of dissymmetry functions and kinds of correlative dependences, the most acceptable for these reasons, were revealed. Dissymmetry functions formed on the basis of atom refractions (polarizabilities) describe the influence of the molecular structures of chiral compounds on the twisting power with higher accuracy than those that characterize the dissymmetry of the atomic masses distribution, according to the important role of the dispersion forces in the formation of helical ordering in liquid crystalline systems. The components characterizing the distribution dissymmetry of atomic refractions and masses with respect to the long and two shorter axes as the peculiar characteristics of biaxiality of chiral molecules describe the influence of the molecular structure on the twisting power with the same accuracy as the general DF do. Thus influence of chiral dopant molecules on the interactions between molecules in the uniaxial mesophases is negligible within the limits of the DF method. Based on the calculations for model systems it is established that the presence of the non-linear cinnamoyl fragment has a decisive influence on the molecular dissymmetry of the chiral α,β-unsaturated ketones. The alkyl groups influence the molecular dissymmetry only slightly, but it is important that their presence ensures the stabilization of the chiral conformer with the defined helicity of the cinnamoyl fragment.
Zusätzliches Material:
1 Ill.
Materialart:
Digitale Medien
URL:
http://dx.doi.org/10.1002/poc.610050605
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