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  • Life and Medical Sciences  (12)
  • General Chemistry  (10)
  • Engineering General  (5)
  • Atomic, Molecular and Optical Physics  (3)
  • organoiron  (2)
  • Wiley-Blackwell  (32)
  • American Chemical Society
  • Cell Press
  • 1990-1994  (31)
  • 1930-1934  (1)
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  • Wiley-Blackwell  (32)
  • American Chemical Society
  • Cell Press
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  • 1
    Electronic Resource
    Electronic Resource
    Calculations on the electronic structure and spectroscopy of C60 and C70 cage structures (1991)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 40 (1991), S. 557-568 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A study of the electronic structure and spectroscopy of models of C60 and C70 cage structures has been carried out using the intermediate neglect of differential overlap (INDO) model Hamiltonian. The geometry for these cages was obtained using gradient-driven methods, and at least in the case of C60, where information is available, is in good accord with the calculations of others. Using a small active space of only single excitations, both configuration interaction (CI) and random phase approximations (RPA) yield spectra in excellent agreement with that obtained from recent experiments. The oscillator strength of the band calculated at ∼47000 cm-1, however, dramatically diminishes as the active space is increased, even though the sum rule increases. We discuss this interesting observation as well as the calculated structure and spectrum of C70.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560400849
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  • 2
    Electronic Resource
    Electronic Resource
    Calculation of 13C-NMR chemical shift using the intermediate neglect of differential overlap model (1992)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 43 (1992), S. 327-342 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The local origin/local orbital (LORG) method of Hansen and Bouman has been implemented with the intermediate neglect of differential overlap Hamiltonian for spectroscopy (INDO/S). The method is shown capable of demonstrating the inductive effects associated with electron-withdrawing substituents through the diamagnetic shielding term. In addition, the method is capable of differentiating chemical shift in differing bond environments. The calculated paramagnetic contribution, however, is deficient for substituents that saturate the minimal basis such as oxygen and fluorine, which severely limits the general utility of the procedure. Through the utilization of reduced linear equations for the paramagnetic term, the method is amenable to any molecule for which a self-consistent field can be performed and therefore can potentially be used to study very large systems. At present, however, the LORG method when used with the rapid INDO/S model Hamiltonian does not reliably reproduce the paramagnetic contribution to the shielding.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560430304
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  • 3
    Electronic Resource
    Electronic Resource
    On the calculation of oscillator strength for electronic transitions using “effective core” methods (1992)
    New York, NY : Wiley-Blackwell
    International Journal of Quantum Chemistry 44 (1992), S. 475-486 
    Details
    ISSN: 0020-7608
    Keywords: Computational Chemistry and Molecular Modeling ; Atomic, Molecular and Optical Physics
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: We examine the effect on calculated oscillator strengths for electronic transitions caused by reintroducing the nodes of valence orbitals in effective core methods through a simple Schmidt orthogonalization. This refinement is then tested within the Intermediate Neglect of Differential Overlap (INDO) model, a valence orbital only model, in both configuration interaction and Random-Phase Approximation (RPA) calculations. It is shown that the differences in oscillator strengths calculated using the dipole-length and dipole-velocity formulations are reduced somewhat for π → * transitions and significantly for n → π* transitions. The oscillator strengths calculated from the dipole-length formalism by the RPA model are in best accord with experiment. © 1992 John Wiley & Sons, Inc.
    Additional Material: 5 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/qua.560440843
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  • 4
    Electronic Resource
    Electronic Resource
    Axial and paraxial influences on limb morphogenesis (1991)
    New York, NY : Wiley-Blackwell
    Journal of Morphology 208 (1991), S. 367-379 
    Details
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: Previous studies by Stephens and McNulty and Strecker and Stephens have demonstrated that foil barriers placed between the mesonephros and lateral plate at stages 12 to 15 inhibited limb development, but foil barriers placed between the neural tube and somites at stages 11 to 12 resulted in limbs with normal skeletal patterns. It was concluded that some influence present in the paraxial region of the embryo at stages 11 to 15 is necessary for normal limb development. The present study was undertaken to localize that influence more precisely. Foil barriers were placed in the lateral edge of the somites or segmental plate of stage 10 to 15 chick embryos. Barriers placed into stage 13 to 15 embryos resulted in chicks with normal limbs, but barriers placed into stage 10 to 11 embryos resulted in chicks with defective limbs. Barriers inserted just lateral to Hensen's node at stages 6 to 8 resulted in embryos with defective or absent wings. We also grafted stage 4 to 9 presumptive limb territories with and without Hensen's node. Explants without Hensen's node formed limb-like structures in 1% of the cases. Explants with Hensen's node formed limb-like structures in 27% of the cases. When barriers were implanted and a node was placed on the lateral side of the barrier, limbs formed in 40% of the cases. These data suggest a medial to lateral progression of some as yet unknown morphogenetic influence necessary for normal limb development and we hypothesized that the influence may initially emanate from Hensen's node.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jmor.1052080310
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  • 5
    Electronic Resource
    Electronic Resource
    Sensilla on the mouthparts and antennae of the elephant louse, Haematomyzus elephantis piaget (Phthiraptera: Haematomyzidae) (1992)
    New York, NY : Wiley-Blackwell
    Journal of Morphology 214 (1992), S. 333-340 
    Details
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The labial palpus of the elephant louse Haematomyzus elephantis has six sensilla that represent three different types: trichoid, basiconic, and styloconic. Two rows of basiconic sensilla are situated on the dorsal and ventral surfaces of the rostrum, and each row consists of three sensilla. Male and female antennae have 15-17 trichoid sensilla situated on the scape, pedicel, and three antennal annuli. Both sexes have two sensilla basiconica on the dorsal surface of the pedicel near the junction of the scape and pedicel. Two coeloconic (tuft) sensilla are situated on the antennae of both sexes, one sensillum on each of the last two annuli. There are three plate organs, two on the last annulus and one on the penultimate annulus of the male and female antennae. Sexual dimorphism is exhibited in the male and female antennae, in that the male has about twice as many sensilla basiconica on the apex of the last annulus as does the female. The total number of sensilla basiconica on the apex of the male antennae is at least two times the number that is known to be present in any other species of lice. © 1992 Wiley-Liss, Inc.
    Additional Material: 14 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jmor.1052140308
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  • 6
    Electronic Resource
    Electronic Resource
    The genitalia of the Indian mollusk Indoplanorbis exustusContribution from the Museum of Natural History, University of Illinois, No. 71. (1933)
    New York, NY : Wiley-Blackwell
    Journal of Morphology 55 (1933), S. 1-13 
    Details
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The molluscan genus Indoplanorbis is shown to differ markedly from all other members of the family Planorbidae in the generative complex, the vas deferens being encased in a long, flexible tube in which it is freely movable. The preputium of the male complex is shown to be completely evertible from the male opening and to act as a male copulatory organ. The presence of a single, heavy penial retractor innervated by an equally strong nerve is indicated. Comparisons are made with the genitalia of the European Coretus and the American Helisoma showing fundamental differences in the generative apparatus of the three groups. Indoplanorbis is most closely related to Coretus, the vas deferens of that group being also encased in a tube. Helisoma differs from both of these genera, the vas deferens not being encased in a tube and is of the same diameter throughout its length.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jmor.1050550102
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  • 7
    Electronic Resource
    Electronic Resource
    A non-linearly stable implicit finite element algorithm for hypersonic aerodynamics (1992)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 34 (1992), S. 419-441 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A generalized curvilinear co-ordinate Taylor weak statement implicit finite element algorithm is developed for the two-dimensional and axisymmetric compressible Navier-Stokes equations for ideal and reacting gases. For accurate hypersonic simulation, air is modelled as a mixture of five perfect gases, i.e. molecular and atomic oxygen and nirogen as well as nitric oxide. The associated pressure is then determined via Newton solution of the classical chemical equilibrium equation system. The directional semi-discretization is achieved using an optimal metric data Galerkin finite element weak statement, on a developed ‘companion conservation law system’, permitting classical test and trial space definitions. Utilizing an implicit Runge-Kutta scheme, the terminal algorithm is then non-linearly stable, and second-order accurate in space and time on arbitrary curvilinear co-ordinates. Subsequently, a matrix tensor product factorization procedure permits an efficient numerical linear algebra handling for large Courant numbers. For ideal- and real-gas hypersonic flows, the algorithm generates essentially non-oscillatory numerical solutions in the presence of strong detached shocks and boundary layer inviscid flow interactions.
    Additional Material: 9 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620340203
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  • 8
    Electronic Resource
    Electronic Resource
    Accelerated bisection techniques for tri- and quindiagonal matrices (1992)
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 35 (1992), S. 203-218 
    Details
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper considers accelerated bisection methods for calculating the eigenvalues of symmetric tridiagonal and quindiagonal matrices using cubic polynomial interpolation, as well as first and second order Newton iteration. Recursive relations based on the Sturm sequences are presented for the Newton type methods. The relations use a convenient scaling which retains the relative magnitudes in the iterative schemes but which avoids numerical overflow. Numerical examples show a significant increase in convergence rate.
    Additional Material: 3 Tab.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/nme.1620350113
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  • 9
    Electronic Resource
    Electronic Resource
    Phorbol ester-induced transcription of an immediate-early response gene by human T cells is inhibited by co-treatment with calcium ionophore (1994)
    New York, N.Y. : Wiley-Blackwell
    Journal of Cellular Biochemistry 54 (1994), S. 135-144 
    Details
    ISSN: 0730-2312
    Keywords: ETR101 ; Jurkat cells ; transcriptional regulation ; chromosome localization ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Chemistry and Pharmacology , Medicine
    Notes: Human T cells require two discrete signals to initiate their proliferation. In Jurkat T cells the first signal can be provided by the phorbol ester TPA and the second by the calcium ionophore A23187. We have isolated a cDNA from Jurkat T cells representing mRNA induced by TPA but inhibited by simultaneous treatment of the cells with antibody, lectin, or A23187. Sequencing revealed identity of the Jurkat clone to a cDNA, termed ETR101, recently isolated from HL60 promyelocytic leukaemia cells and shown to be an immediate early gene expressed upon TPA stimulation of these cells [Shimizu et al.: J Biol Chem 266:12157, 1991]. The gene is also induced very rapidly upon TPA treatment of Jurkat cells and is superinduced by co-treatment with cycloheximide. The predicted amino acid sequence encoded by ETR101 has weak homology to JunB and JunD, therefore it is of some interest that these three genes share the chromosomal localization, 19p13.2. The divergent effects of TPA treatment upon cell proliferation and differentiation in different circumstances allow some speculation about a possible role for the ETR101 gene product upon cellular differentiation.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jcb.240540202
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  • 10
    Electronic Resource
    Electronic Resource
    Imaging fluid/solid interactions in hydrocarbon reservoir rocks (1993)
    New York, NY [u.a.] : Wiley-Blackwell
    Microscopy Research and Technique 25 (1993), S. 465-473 
    Details
    ISSN: 1059-910X
    Keywords: ESEM ; Liquid hydrocarbons ; Hydrocarbon reservoirs ; Clay minerals ; Chlorite ; Illite/smectite ; Calcite ; Fluid sensitivity ; Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Natural Sciences in General
    Notes: The environmental scanning electron microscope (ESEM) has been used to image liquid hydrocarbons in sandstones and oil shales. Additionally, the fluid sensitivity of selected clay minerals in hydrocarbon reservoirs was assessed via three case studies: HCl acid sensitivity of authigenic chlorite in sandstone reservoirs, freshwater sensitivity of authigenic illite/smectite in sandstone reservoirs, and bleach sensitivity of a volcanic reservoir containing abundant secondary chlorite/corrensite. The results showed the suitability of using ESEM for imaging liquid hydrocarbon films in hydrocarbon reservoirs and the importance of simulating in situ fluid-rock interactions for hydrocarbon production programmes. In each case, results of the ESEM studies greatly enhanced prediction of reservoir/borehole reactions and, in some cases, contradicted conventional wisdom regarding the outcome of potential engineering solutions. © 1993 Wiley-Liss, Inc.
    Additional Material: 10 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/jemt.1070250518
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