ISSN:
0030-493X
Keywords:
Chemistry
;
Analytical Chemistry and Spectroscopy
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Photodissociation experiments and ion/molecule reactions with pyridine and hex-1-ene show that [C3H6O]+· ions from propylene oxide isomerize to the vinyl metbyl ether structure. [C3H6O]+· fragment ions from methyl-substituted 1,3-dioxolanes have lower internal energies. In these cases a mixture of photodissociating ring-opened propylene oxide ions and vinyl methyl ether ions is observed.
Additional Material:
2 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/oms.1210250604
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