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  • American Institute of Physics (AIP)  (3)
  • 1990-1994  (3)
  • 1940-1944
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  • 1
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 93 (1990), S. 416-427 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We examine the effects of interactive noise, i.e., noise which is processed by the system, on the Brusselator, a nonlinear oscillator. The Brusselator is investigated for three types of motion: periodic, quasiperiodic, and chaotic. Fluctuations are imposed on the system variables (Type V noise). The average fluctuation amplitudes are chosen between 10 and 10 000 ppm (1%) and they are Gaussian distributed. The simulated time series are analyzed by autocorrelation functions, Fourier spectra, Poincaré sections, one-dimensional maps, maximum Lyapunov exponents, and correlation dimensions. As a result, noisy periodic and quasiperiodic motion can be distinguished from deterministic chaos if the fluctuation amplitude is sufficiently small. The generic structure of the attractor can be recognized when Lyapunov exponents or correlation dimensions are extrapolated to zero fluctuation amplitude. Quasiperiodic attractors in the Brusselator are obscured even by small amounts of noise. Chaos in the Brusselator, on the other hand, is found to be robust against noise. For periodic motion we show that points close to a bifurcation exhibit a stronger sensitivity towards noise than points far away. In the log–log plots for the correlation dimension we observed break points for noisy periodic and quasiperiodic motion. They separate the noise from the purely deterministic part of the motion. For increasing noise levels the break points move to higher length scales of the attractor. Break points were not found for chaos in the Brusselator nor in the Lorenz and Rössler models. In the Brusselator very large noise levels beyond 1% obscure the deterministic structure even of a chaotic attractor so that any clear distinction between chaos and noise induced (statistical) aperiodicity is no longer possible. Implications on experimental systems are discussed.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 98 (1993), S. 5771-5776 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We report the experimental measurement of a stochastic potential in a bistable chemical system, the iodate–arsenous acid reaction. The reaction, run in a continuous flow stirred tank reactor, is driven by a fluctuating reactant flow which causes the system to move randomly between the two stable steady states. We calculate the probability of the system being in a particular state, and the probability distributions depend on the average flow rate. The experimental results are in agreement with predictions of the Fokker–Planck equation.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    College Park, Md. : American Institute of Physics (AIP)
    The Journal of Chemical Physics 101 (1994), S. 5126-5135 
    ISSN: 1089-7690
    Source: AIP Digital Archive
    Topics: Physics , Chemistry and Pharmacology
    Notes: We extend previous work describing the passive electrical coupling of two periodic chemical states to include quasiperiodic and chaotic states. Our setup resembles an electrochemical concentration cell (a battery) whose half cells [continuous-flow stirred tank reactors (CSTRs)] each contain the Belousov–Zhabotinsky (BZ) reaction. For a closed electrical circuit the two half cells are weakly coupled by an external variable resistance and by a constant low mass flow. This battery may produce either periodic, quasiperiodic, or chaotic alternating current depending on the dynamic BZ states chosen in the half cells. A lower fractal dimensionality is calculated from the electrical potential of a single chaotic CSTR than from the difference potential (relative potential) of the two chaotic half cell potentials. A similar situation is observed in model calculations of a chaotic spatiotemporal system (the driven Brusselator in one space dimension) where the dimensionality derived from a local time series is lower than the dimensionality of the global trajectory calculated from the Karhunen–Loeve coefficients.
    Type of Medium: Electronic Resource
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