ALBERT

Description: Measurements from two independent satellite data sets have been used to derive the climatology of the integrated amount of ozone in the troposphere. These data have led to the finding that large amounts of ozone pollution are generated by anthropogenic activity originating from both the industrialized regions of the Northern Hemisphere and from the southern tropical regions of Africa. To verify the existence of this ozone anomaly at low latitudes, an ozonesonde capability has been established at Ascension Island (8 deg S, 15 deg W) since July 1990. According to the satellite analyses, Ascension Island is located downwind of the primary source region of this ozone pollution, which likely results from the photochemical oxidation of emissions emanating from the widespread burning of savannas and other biomass. These in situ measurements confirm the existence of large amounts of ozone in the lower atmosphere. A summary of these ozonesonde data to date will be presented. In addition, we will present some ozone profile measurements from SAGE II which can be used to provide upper tropospheric ozone measurements directly in the tropical troposphere. A preliminary comparison between the satellite observations and the ozonesonde profiles in the upper troposphere and lower stratosphere will also be presented.

Description: Recent analyses of long-term records of tropospheric ozone measurements in the Northern Hemisphere suggest that it is increasing at a rate of 1 to 2 percent per year. Because of this, it is argued that the amount of atmospheric warming due to increasing tropospheric ozone is comparable to, or possibly even greater than, the amount of warming due to the increase of carbon dioxide. Unlike all other climatically important trace gases, ozone is toxic, and increases in its concentration will result in serious environmental damage, as well as impairment of human health.

Description: The data sets obtained from instruments that have measured carbon monoxide and tropospheric ozone from space are reviewed. These instruments include a gas cell correlation radiometer named MAPS (Measurement of Air Pollution from Satellites), the Total Ozone Mapping Spectrometer, and the Stratospheric Aerosol and Gas Experiment. Particular attention is given to differential absorption lidar technology which can determine the vertical distribution of aerosols and selected trace gases with considerably more resolution than passive remote sensing techniques. The current plans for monitoring pollution from spaceborne platforms are also discussed.

Description: Vertical profiles of ozone obtained from ozonesondes in Brazzaville (Congo) and Ascension Island show that large quantities of tropospheric ozone are present over southern Africa and the adjacent eastern tropical South Atlantic Ocean. The origin of this pollution is widespread biomass burning in Africa. These measurements support satellite-derived tropospheric ozone data that demonstrate that ozone originating from this region is transported throughout most of the Southern Hemisphere. Seasonally high levels of CO2 and methane observed at middle- and high-latitude stations in Africa, Australia, and Antarctica likely reflect the effects of this distant biomass burning. These data suggest that even the most remote regions on this planet may be significantly more polluted than previously believed.

Description: Measurements of lower stratospheric ozone in the Tropics using electrochemical concentrations cell (ECC) sondes and the airborne UV Differential Absorption Lidar (DIAL) system after the eruption of Mt. Pinatubo are compared with the Stratospheric Aerosol and Gas Experiment 2 (SAGE 2) and ECC sonde measurements from below the eruption to determine what changes have occurred as a result. Aerosol data from the Advanced Very High Resolution Radiometer (AVHRR) and the visible and IR wavelengths of the lidar system are used to examine the relationship between aerosols and ozone changes. Ozone decreases of 30 percent at altitudes between 19 and 26 km, partial column (16-28 km) decreases of about 27 D.U., and slight increases (5.4 D.U.) between 28 and 31 km are found in comparison with SAGE 2 climatological values.

Description: Data from the NASA dry-season Amazon boundary layer experiment (ABLE2A) is used with a 1D tropospheric photochemical model to analyze the atmospheric chemistry in the region and determine the impact of the long-range transport of biomass-burning emissions. Inputs of surface sources and the deposition of various species measured during ABLE2A are employed to simulate the background atmosphere, and haze characteristics are introduced for a 12-hr simulation. The in situ ozone production rate doubles during the period of haze when hydrocarbons are present. The model predicts that the production of ozone is enhanced during the dry season, and that increased ozone during the southern tropical burning season is related to the regional transport of haze.

Description: The influence of volcanic aerosols on stratospheric ozone is a topic of current interest, especially with the June 15, 1991 eruption of Mt. Pinatubo in the Philippines. Lidar has been used in the past to provide aerosol profiles which could be compared with ozone profiles measured using ozonesondes to look for coincidences between volcanic aerosols and ozone decreases. The differential absorption lidar (DIAL) technique has the advantages of being able to measure ozone and aerosol profiles simultaneously as well as being able to cover large geographical regions rapidly. While there are problems associated with correcting the ozone profiles for the presence of aerosols, the corrections can be made reliably when the wavelengths are closely spaced and the Bernoulli method is applied. The DIAL measurements considered in this paper are those obtained in the tropical stratosphere in January 1992 during the Airborne Arctic Stratospheric Expedition (AASE-II). The determination of ozone profiles in the presence of Pinatubo aerosols is discussed in a companion paper.

Description: The large amount of sulfuric acid aerosol formed in the stratosphere by conversion of sulfur dioxide emitted by the eruption of Mount Pinatubo (15.14 deg N, 120.35 deg E) in the Philippines around June 15, 1991, has had a pronounced effect on lower stratospheric ozone in the tropics. Measurements of stratospheric ozone in the tropics using electrochemical concentration cell (ECC) sondes before and after the eruption and the airborne UV differential absorption lidar (DIAL) system after the eruption are compared with Stratospheric Aerosol and Gas Experiment II (SAGE II) measurements from several years before the eruption and ECC sonde measurements from the year prior to the eruption to determine the resulting changes. Ozone decreases of up to 33 % compared with SAGE II climatological values were found to be directly correlated with altitude regions of enhanced aerosol loading in the 16- to 28-km range. A maximum partial-column decrease of 29 +/- Dobson units (DU) was found over the 16- to 28-km range in September 1991 along with small increases (to 5.9 +/- 2 DU) from 28 to 31.5 km. A large decrease of ozone was also found at 4 deg to 8 deg S from May to August 1992, with a maximum decrease of 33 +/- 7 DU found above Brazzaville in July. Aerosol data form the visible channel of the advanced very high resolution radiometer (AVHRR) and the visible wavelength of the UV DIAL system were used to examine the relationship between aerosol (surface area) densities and ozone changes. The tropical stratospheric ozone changes we observed in 1991 and 1992 are likely be explained by a combination of dynamical (vertical transport) perturbations, radiative perturbations on ozone photochemistry, and heterogeneous chemistry.

Description: Carbon monoxide mixing ratios obtained by the October 1984 Measurement of Air Pollution from Satellites (MAPS) experiment are compared with the distribution of October 1984 Total Ozone Mapping Spectrometer (TOMS) ozone concentrations. The TOMS and MAPS data show coincident high values of ozone and carbon monoxide over central South America and southeastern Africa. The 1984 MAPS data are also compared with tropospheric ozone concentrations derived from 6 years of TOMS and Stratospheric Aerosol and Gas Experiment (SAGE) I and II measurements. Examination of the October climatological distribution of tropospheric ozone also reveals high concentrations over central South America and southeastern Africa. These coincident high values of CO and ozone in the rural southern tropics are most likely due to biomass burning and the subsequent transport of CO and ozone by large-scale weather patterns. It appears that both CO and ozone are being transported thousands of kilometers from their source regions by the prevailing winds.

Description: A comparison conducted between direct measurements of Brazilian ozone and NO concentrations and space-based measurements has indicated a strong correlation between the two environmental sensing methods and indicated the seasonality of both ozone and CO concentrations in this region. Dry season increases appear to be due to both increased local biomass burning and the transport of CO and ozone from Africa. The coincident high values of both CO and ozone suggest photochemical sources, rather than a stratospheric source, for the African and South American ozone.