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  • Chemistry
  • Picea glauca Calamagrostis Vaccinium
  • 1990-1994  (1)
  • 1955-1959  (1)
  • 1
    ISSN: 1432-1939
    Keywords: Boreal forest ; Nitrogen, phosphorus, and cation nutrition ; Stable isotopes ; Picea glauca Calamagrostis Vaccinium
    Source: Springer Online Journal Archives 1860-2000
    Topics: Biology
    Notes: Abstract Natural abundances of nitrogen isotopes, δ15N, indicate that, in the same habitat, Alaskan Picea glauca and P. mariana use a different soil nitrogen compartment from the evergreen shrub Vaccinium vitis-idaea or the deciduous grass Calamagrostis canadensis. The very low δ15N values (-7.7 ‰) suggest that (1) Picea mainly uses inorganic nitrogen (probably mainly ammonium) or organic N in fresh litter, (2) Vaccinium (-4.3 ‰) with its ericoid mycorrhizae uses more stable organic matter, and (3) Calamagrostis (+0.9 ‰) exploits deeper soil horizons with higher δ15N values of soil N. We conclude that species limited by the same nutrient may coexist by drawing on different pools of soil N in a nutrient-deficient environment. The differences among life-forms decrease with increasing N availability. The different levels of δ15N are associated with different nitrogen concentrations in leaves, Picea having a lower N concentration (0.62 mmol g−1) than Vaccinium (0.98 mmol g−1) or Calamagrostis (1.33 mmol g−1). An extended vector analysis by Timmer and Armstrong (1987) suggests that N is the most limiting element for Picea in this habitat, causing needle yellowing at N concentrations below 0.5 mmol g−1 or N contents below 2 mmol needle−1. Increasing N supply had an exponential effect on twig and needle growth. Phosphorus, potassium and magnesium are at marginal supply, but no interaction between ammonium supply and needle Mg concentration could be detected. Calcium is in adequate supply on both calcareous and acidic soils. The results are compared with European conditions of excessive N supply from anthropogenic N depositions.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Zeitschrift für anorganische Chemie 282 (1955), S. 232-240 
    ISSN: 0044-2313
    Keywords: Chemistry ; Inorganic Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Bei der Einwirkung von in flüssigem Ammoniak gelöstem Lithium, Natrium, Kalium, Rubidium und Cäsium auf Graphit oder bei der Umsetzung der bekannten Alkaligraphitverbindungen mit flüssigem NH3 entstehen sehr reaktionsfähige Graphitverbindungen, in denen Metallatome und NH3-Molekeln in das Gitter eingelagert sind. Es konnten bisher dargestellt werden: eine blaue Verbindung mit der angenäherten Zusammensetzung C12Me(NH3)2 und der Struktur einer 1. Stufe, sowie eine alkaliärmere, schwarze Verbindung, etwa C28Me(NH3)2 mit der Struktur einer 2. Stufe.Lithium, gelöst in Methylamin, gibt mit Graphit eine blaue 1. Stufe mit der Idealformel C12Li(CH3NH2)2.Durch die Einlagerung vergrößert sich der Abstand benachbarter C-Ebenen im Graphit von 3,35 auf 6,6 kX bei allen Ammoniakaten und auf 6,9 kX bei der Methylaminverbindung.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
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