ISSN:
0009-2940
Keywords:
Ozonolysis
;
Cycloalkylidenecycloalkanes
;
Dispiro-1,2,4-trioxolanes
;
Thermolysis
;
Photolysis
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Dispiro-1,2,4-trioxolanes by Ozonolysis of Cycloalkylidenecycloalkanes on PolyethyleneOzonolyses of symmetrical (1b - d) and of unsymmetrical cycloalkylidenecycloalkanes (8a, b) afforded the dispiro-1,2,4-trioxolanes 4b - d and 9a, b, respectively. Their thermal decompositions gave mixtures of the cyclic ketones (3) and lactones (6). Photolyses afforded in addition to 3 and 6 the cyclic anhydrides 13, which are isomeric with the corresponding dispiro-1,2,4-trioxolanes.
Additional Material:
1 Ill.
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19911240224
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