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  • 36.40. + d  (1)
  • Crystal water  (1)
  • poly(vinylbutyral)
  • rhamnolipids
  • 1990-1994  (4)
  • 1960-1964
  • 1930-1934
  • 1925-1929
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Verlag/Herausgeber
Erscheinungszeitraum
  • 1990-1994  (4)
  • 1960-1964
  • 1930-1934
  • 1925-1929
Jahr
  • 1
    Digitale Medien
    Digitale Medien
    Springer
    European biophysics journal 21 (1992), S. 313-320 
    ISSN: 1432-1017
    Schlagwort(e): Monte Carlo ; Crystal water ; Structure refinement
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Biologie , Physik
    Notizen: Abstract The space in the unit cell of a metmyoglobin crystal not occupied by myoglobin atoms was filled with water using Monte Carlo calculations. Independent calculations with different amounts of water have been performed. Structure factors were calculated using the water coordinates thus obtained and the known coordinates of the myoglobin atoms. A comparison with experimental structure factors showed that both the low and the high resolution regime could be well reproduced with 814 Monte Carlo water molecules per unit cell with a B-value of 50 Å2. The Monte Carlo water molecules yield a smaller standard R-value (0.166) than using a homogeneous electron density for the simulation of the crystal water (R = 0.212). A reciprocal space refinement of the water and the protein coordinates has been performed. Monte Carlo calculations can be used to obtain information for crystallographically invisible parts of the unit cell and yield better coordinates for the visible part in the refinement.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 2
    ISSN: 1573-4986
    Schlagwort(e): fast atom bombardment ; tandem mass spectrometry ; rhamnolipids ; Pseudomonas sp
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie
    Notizen: Abstract Two rhamnobiose-lipid preparations have been studied by fast atom bombardment (FAB) tandem mass spectrometry. The principal rhanobiose-lipids contain the β-hydroxydecanoyl-β-hydroxydecanoate Rha-Rha-C10-C10 and the β-hydroxytetradecanoyl-β-hydroxytetradecanoate Rha-Rha-C14-C14. Both preparations contain minor components which are heterogenous in β-hydroxy fatty acid composition. FAB ionization of rhamnobiose-lipids in the presence of Na+ shows the formation of both [M + Na]+, [M + 2Na - H]+, [M + 3Na - 2H]+ and [M - H]− ions. Tandem mass spectrometry of the [M + 2Na - H]+ and [M - H]− ions give information about the sequence of the building blocks. Particularly, heterogeneity in β-hydroxy fatty acid composition is determined for the principal components and all the minor components present in the preparations.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 3
    Digitale Medien
    Digitale Medien
    Springer
    Colloid & polymer science 269 (1991), S. 1077-1085 
    ISSN: 1435-1536
    Schlagwort(e): Aluminum oxide ; adsorption ; light scattering ; fish oil ; poly(vinylbutyral)
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Chemie und Pharmazie , Maschinenbau
    Notizen: Abstract The effects of added poly(vinylbutyral) (PVB) and oxidized Menhaden fish oil (O-FO) on dilute suspensions of Al2O3 in the azeotropic solvent mixture 73/27 Wt.-% trichloroethylene/ethanol were studied by static (SLS) and dynamic light-scattering (DLS). The DLS correlation function consisted of four terms from: 1) interdiffusion of the two solvents, 2) diffusion of Al2O3, 3) diffusion of added O-FO and/or PVB, and 4) an induced velocity of particles through the scattering volume due to “laser pressure.” The amplitude and relaxation time of all terms could be determined. Addition of PVB to the Al2O3 suspension resulted in an increase in particle size corresponding to the adsorption of a monolayer of coils. Addition of O-FO to the Al2O3 suspension did not produce a significant increase in particle size, indicating either no adsorption or a compact conformation of O-FO molecules on the Al2O3 surface.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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  • 4
    Digitale Medien
    Digitale Medien
    Springer
    The European physical journal 20 (1991), S. 33-34 
    ISSN: 1434-6079
    Schlagwort(e): 36.40. + d
    Quelle: Springer Online Journal Archives 1860-2000
    Thema: Physik
    Notizen: Abstract A tandem time-of-flight mass spectrometer is used to measure photofragmentation mass spectra and optical absorption spectra of mass selected argon cluster ions in then=3 to 108 atoms per cluster range.
    Materialart: Digitale Medien
    Standort Signatur Erwartet Verfügbarkeit
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