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Asymmetrische Synthese chiraler Phosphorverbindungen durch destruktiv-Oxidation von P(III)-Verbindungen mittels chiraler Oxaziridine (1991)

Verfürth, Uwe ; Ugi, Ivar

Weinheim : Wiley-Blackwell

Berichte der deutschen chemischen Gesellschaft 124 (1991), S. 1627-1634

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ISSN: 0009-2940

Keywords: Stereoselectivity, destructive ; Phosphite oxidation ; Oxaziridines, chiral ; Chemistry ; Inorganic Chemistry

Source: Wiley InterScience Backfile Collection 1832-2000

Topics: Chemistry and Pharmacology

Notes: Asymmetric Synthesis of Chiral Phosphorus Compounds by Destructive-Selective Oxidation of P(III) Compounds by Means of Chiral OxaziridinesFrom camphor and fenchone chiral N -sulfonyloxaziridines (e.g, 7,13) are available that are well-suited for the destructive-stereoselective oxidation of P(III) compounds 16. Optimum reagents and reaction conditions for this oxidation are determined by a systematic study. Chiral P(III) and P(V) compounds can thus be prepared from racemic P(III) derivatives.

Additional Material: 2 Ill.

Type of Medium: Electronic Resource

URL: http://dx.doi.org/10.1002/cber.19911240725

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