ISSN:
0009-2940
Keywords:
Bond activation, C-F, intermolecular
;
14-Electron intermediates
;
Platinum complexes
;
Chemistry
;
Inorganic Chemistry
Source:
Wiley InterScience Backfile Collection 1832-2000
Topics:
Chemistry and Pharmacology
Notes:
Reductive elimination of neopentane from cis-hydridoneopentyl[η2-bis(di-tert-butylphosphanyl)methane]platinum (II), (dtbpm)Pt(Np)(H) (1), allows to generate the 14-electron fragment [(dtbpm)Pt(0)] (2) at ambient temperature. This highly reactive intermediate is capable of activating C-F bonds of hexafluorobenzene, yielding exclusively the C-F insertion product (dtbpm)Pt(C6F5)F (3).
Type of Medium:
Electronic Resource
URL:
http://dx.doi.org/10.1002/cber.19921250319
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