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  • Articles  (571)
  • Engineering  (425)
  • Physical Chemistry  (128)
  • Gas chromatography
  • Wiley-Blackwell  (571)
  • 1990-1994  (414)
  • 1975-1979  (157)
  • 1
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 8 (1976), S. 23-24 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 11 (1979), S. 175-185 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Relaxation rates for O2(1Σg+) by nonradiative pathways have been determined using the fast-flow technique. O2(1Σg+) is formed from O2(1Δg) by an energy pooling process. O2(1Δg) is generated by passing purified oxygen through a microwave discharge. Oxygen atoms are removed by distilling mercury vapor through the discharge zone. It has been observed that the wall loss rate for O2(1Σg+) decreases with increasing pressure of oxygen and thus appears to be diffusion controlled. Quenching rate constants for O2, N2, and He have been determined and found to be (1.5 ± 0.1) × 104, (1.0 ± 0.05) × 106 and (1.2 ± 0.1) × 105 l./mol·sec, respectively.
    Additional Material: 6 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    International Journal for Numerical Methods in Fluids 15 (1992), S. 273-295 
    ISSN: 0271-2091
    Keywords: Navier-Stokes ; ILU(l) ; Preconditioned conjugate gradient ; Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Notes: A robust technique for solving primitive variable formulations of the incompressible Navier-Stokes equations is to use Newton iteration for the fully implicit non-linear equations. A direct sparse matrix method can be used to solve the Jacobian but is costly for large problems; an alternative is to use an iterative matrix method. This paper investigates effective ways of using a conjugate-gradient-type method with an incomplete LU factorization preconditioner for two-dimensional incompressible viscous flow problems. Special attention is paid to the ordering of unknowns, with emphasis on a minimum updating matrix (MUM) ordering. Numerical results are given for several test problems.
    Additional Material: 9 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 25 (1993), S. 521-537 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: A laser flash photolysis-long path absorption technique has been employed to study the kinetics of the reaction products as a function of temperature (248-346 K), pressure (16-800 torr), and buffer gas identity (N2, CF4). The reaction is found to be in the falloff regime between third and second-order over the entire range of conditions investigated. This is the first study where temperature-dependent measurements of k1(P, T) have been reported at pressures greater than 12 torr; hence, our results help constrain choices of k1(P, T) for use in models of lower stratospheric BrOx chemistry. Approximate falloff parameters in a convenient form for atmospheric modeling are derived. © 1993 John Wiley & Sons, Inc.
    Additional Material: 9 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    International Journal of Chemical Kinetics 25 (1993), S. 805-817 
    ISSN: 0538-8066
    Keywords: Chemistry ; Physical Chemistry
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: This article describes the first direct determination of the rate coefficient for the self-reaction between two NO3 radicals. A laser photolysis technique was used to generate NO3, and time-resolved decays of NO3 were followed after stopping the photolysis. The products of the reaction are inferred to be NO2 and O2. The derived rate coefficient at room temperature for the self-reaction of (2.3 ± 0.8) ×10-16 cm3 molecule-1s-1 is in excellent agreement with the only other data, which were obtained in an indirect study. Consideration is given to the magnitude and influence of secondary chemistry and to the participation of FO in the chemistry of the NO3 buildup phase. The studies were conducted over a pressure range of 8 to 100 torr in helium. No clear pressure dependence was observed, and some tentative inferences are drawn both from this result and from the absolute magnitude of the rate coefficient about the mechanism of the reaction. There is apparently no role for the reaction in the chemistry of the atmosphere. © 1993 John Wiley & Sons, Inc.
    Additional Material: 7 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 29 (1990), S. 647-663 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A new algorithm family taking into account the entire loading process in a single large time increment is proposed to compute structures with physical non-linearities and is tested on some examples in elastoplasticity. The method considerably reduces the number of transfers between local and global levels, hence the numerical cost of calculation is also diminished.
    Additional Material: 14 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 29 (1990), S. 1109-1130 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: This paper discusses various procedures for the implementation of viscoplastic constitutive equations in Finite Element Codes. The set of constitutive equations that has been used is described. Several kinds of implementation, using various numerical techniques, are proposed. Validations of these implementations and comparisons between them are investigated by means of a set of simple but comprehensive examples.
    Additional Material: 7 Ill.
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  • 8
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 33 (1992), S. 943-961 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: We investigate the Generalized Midpoint Rule for the time integration of elastoplastic constitutive equations for pressure-independent yield criteria. The incremental equations are divided into one scalar hydrostatic pressure/dilation rate equation, and a stress deviator/strain rate deviator tensorial equation, the solution of which reduces to one single scalar equation in the plastic multiplier. The existence and uniqueness of an incremental solution is discussed. The pressure/deviator decomposition is the basis for reduced integration of the pressure term in the Principle of Virtual Work, in order to avoid locking and spurious pressure oscillations. It is also shown that an optimal choice of the parameter of the Midpoint Rule can be computed by reference to the analytical solution of the equations assuming no work hardening. A benchmark test shows that this choice allows increased time steps. This formulation is applied to two classical problems: bulging of a tube under internal pressure and tension test on a notched specimen, and a comparison with the analytical solution is performed. Finally, the hypothesis which sustains these formulations of elastoplasticity (constant strain rate during an increment) is discussed with reference to elastic unloading and residual stress computation.
    Additional Material: 10 Ill.
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  • 9
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 34 (1992), S. 485-506 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The present report deals with many applications of different numerical methods to calculations of three-dimensional stationary supersonic flows around aerodynamic configurations. Both an inviscid non-heat-conducting perfect gas and a real high-temperature gas with physical-chemical processes are considered. The results of some investigations carried out during recent years in the U.S.S.R. are reviewed. A brief description of applicable numerical methods is presented. A number of results are discussed both for separate parts of a flying vehicle and for whole configurations. Some gasdynamic effects, and aerodynamic and thermal characteristics are analysed. Among the aerodynamic elements we consider pointed and blunted nose parts of configurations, air intakes, wing and stabilizers. Also more complicated cases are considered such as compound aerodynamic objects and configurations modelling different kinds of whole flying vehicles (missile, aircraft, spacecraft).
    Additional Material: 21 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 34 (1992), S. 1015-1033 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: Hydrated soft tissues of the human musculoskeletal system, such as articular cartilage in diarthrodial joints or the annulus fibrosis of the inter vertebral disk, are accurately represented by a biphasic continuum model consisting of an incompressible solid phase (collagen and proteoglycan) and incompressible, inviscid fluid (interstitial fluid) and derive from the continuum theory of mixtures. These tissues exhibit a viscoelastic-type response which is caused by the diffusive drag of the fluid phase as it flows past the solid phase. In this study an automated, adaptive, finite element solution of the governing biphasic equations is presented. The finite element formulation is based on a mixed-penalty approach in which the penalty form of the continuity equation for the mixture is included in the weak form. Pressure, solid and fluid velocities are interpolated independently, and the coefficients of the C-1 pressure field are eliminated at the element level. The resulting matrix form is a system of first order differential equations which is solved via standard finite difference methods. Mesh generation and updating, including both refinement and coarsening, for the two-dimensional examples examined in this study are performed using Finite Quadtree. The adaptive analysis is based on an error indicator which is the L2 norm of the difference between the finite element solution and a projected finite element solution. Total stress, calculated as the sum of the solid and fluid phase stresses, is used in the error indicator. Rezoning is accomplished by transferring the finite element solution for the primary variables onto the locally updated mesh using a projected field. These projected values allow the finite difference algorithm to proceed in time using the updated mesh. The accuracy and effectiveness of this adaptive finite element analysis is demonstrated using two-dimensional axisymmetric problems corresponding to the uncomined compression of a cylindrical disk of soft tissue and the indentation of a thin sheet of soft tissue. The method is shown to effectively capture the steep gradients in both problems and to produce solutions in good agreement with independent, converged, numerical solutions.
    Additional Material: 13 Ill.
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