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  • Polymer and Materials Science  (4)
  • Magnetic non-equivalence  (1)
  • 1990-1994  (2)
  • 1980-1984  (3)
Collection
Keywords
Publisher
Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Flow properties of ethylene/vinyl acetate copolymers (1981)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 182 (1981), S. 2789-2800 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: A series of linear and branched fractions of an ethylene/vinyl acetate (EVA) copolymer is characterized by viscometry and gel permeation chromatography (GPC) exclusively. Characterization results are applied to the study of the influence of branching on flow properties of concentrated solutions of EVA fractions. Newtonian viscosity-concentration-molecular weight relationships are obtained for both linear and branched samples. Graessley's theory of entanglements for linear polymers is tested with a set of fractions. Experimental flow curves come out to be independent of the linear or branched nature of the samples.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1981.021821024
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  • 2
    Electronic Resource
    Electronic Resource
    Glass transition temperatures in blends of poly(N-vinyl-2-pyrrolidone) with a copolymer of bisphenol A and epichlorohydrin or with poly(vinyl butyral) (1984)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 185 (1984), S. 1761-1766 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Blends of poly(vinyl butyral) (PVB) and of a copolymer of bisphenol A and epichlorohydrin (Phenoxy) with poly(N-vinyl-2-pyrrolidone) (PVP) were prepared by solution casting. The glass transition temperatures Tg for different compositions of the blends were measured by differential scanning calorimetry (DSC). The Tg behaviour of PVB/PVP blends suggests the existence of a single phase for blends containing less than 50 wt.-% PVP, and of two phases in blends containing more than 50 wt.-% PVP. Phenoxy/PVP blends showed to be miscible over the entire composition range. It was found that the Gordon-Taylor equation predicts adequately the Tg-composition dependence with a K parameter equal to 0,5 and 1,25 for PVB/PVP and Phenoxy/PVP blends, respectively.
    Additional Material: 2 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1984.021850822
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  • 3
    Electronic Resource
    Electronic Resource
    Blends of poly(hydroxy ether of bisphenol-A) with poly(2-vinylpyridine) and poly(4-vinylpyridine) (1993)
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 194 (1993), S. 501-510 
    Details
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: Poly(hydroxy ether of Bisphenol-A), so-called Phenoxy resin (structure-based IUPAC name: poly[oxy(2-hydroxytrimethylene)oxy-1,4-phenyleneisopropylidene-1,4-phenylene]), is shown to be miscible with poly(4-vinylpyridine) (P4VPy, poly[1-(4-pyridyl)ethylene]) and poly(2-vinylpyridine) (P2VPy, poly[1-(2-pyridyl)ethylene]) over the entire composition range. Miscibility of the blends is evidenced by their glass transition temperatures being intermediate between the pure polymers for the blends of P4VPy and Phenoxy but being higher than the average for the case of the P2VPy/Phenoxy blends. Hydrogen bonding between the components was detected through infrared spectroscopy, which was also used in the study of mixtures of low-molecular-weight analogues, in order to calculate the free energies of mixing according to the association model of Painter and Coleman.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/macp.1993.021940213
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  • 4
    Electronic Resource
    Electronic Resource
    Chemical modifications of phenoxy resin. Synthesis and 1H NMR study of model compounds (1991)
    Chichester : Wiley-Blackwell
    Organic Magnetic Resonance 29 (1991), S. 1005-1011 
    Details
    ISSN: 0749-1581
    Keywords: Phenoxy resin ; Glycerol derivatives ; Model compounds ; Magnetic non-equivalence ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The hydroxy group of phenoxy resin has been modified by etherification and esterification. The 1H NMR spectra of these products show large differences in the splitting patterns of the methylene protons according to the chemical nature of the substituent groups. Model compounds for phenoxy resin and derivatives, as well as some other glycerol derivatives, have been synthesized in order to study in more detail the signals of the CH2 group. The 1H NMR spectra of these compounds show two types of splitting. In some cases both protons absorb clearly as a doublet through accidental equivalence, while in other cases they are magnetically non-equivalent. This behaviour can be explained by non uniform conformer populations (JAX ≠ JBX) in some cases, but where JAX ≍ JBX it could not be explained without taking into account the molecular asymmetry.
    Additional Material: 7 Ill.
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/mrc.1260291006
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  • 5
    Electronic Resource
    Electronic Resource
    Characteristic ratio of a 1,4-poly(2,3-dimethyl butadiene) (1980)
    New York : Wiley-Blackwell
    Journal of Polymer Science: Polymer Physics Edition 18 (1980), S. 173-174 
    Details
    ISSN: 0098-1273
    Keywords: Physics ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Type of Medium: Electronic Resource
    URL: http://dx.doi.org/10.1002/pol.1980.180180116
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