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  • Analytical Chemistry and Spectroscopy  (5)
  • Engineering General  (5)
  • 1990-1994  (7)
  • 1980-1984  (3)
  • 1
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 15 (1980), S. 733-751 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A concise and efficient algorithm is presented for deriving finite element shape functions from an arbitrary set of independent functions. Based on special one-dimensional interpolatory schemes derived via the algorithm, a variety of two- and three-dimensional interpolatory schemes are developed which are useful for modelling singular behaviour. The methodology presented is general and may be fruitfully applied to the development of ‘special’ finite element shape functions for a variety of other situations.
    Additional Material: 8 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 15 (1980), S. 1413-1418 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: A new finite element procedure is introduced for the analysis of nearly-incompressible media. The approach may be simply implemented by a small change of the standard technique, and is applicable to arbitrary anisotropic and/or nonlinear media. The procedure is shown to specialize to the selective integration and mean-dilatation formulations under appropriate hypothesis.
    Type of Medium: Electronic Resource
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  • 3
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 15 (1980), S. 1862-1867 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: An improved algorithm is presented for integrating rate constitutive equations in large-deformation analysis. The algorithm is shown to be ‘objective’ with respect to large rotation increments.
    Additional Material: 1 Ill.
    Type of Medium: Electronic Resource
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  • 4
    Electronic Resource
    Electronic Resource
    Chichester : Wiley-Blackwell
    Biological Mass Spectrometry 28 (1993), S. 340-343 
    ISSN: 0030-493X
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: Ion-ion coincidence measurements following K-shell absorption in the carbon dioxide molecule were performed by applying time-of-flight mass spectrometry in conjunction with monochromatic synchrotron radiation and electron impact. Identification of particularly sensitive electronic transitions and the consecutive molecular fragmentation in real time was performed. Analysis of coincidence recordings from decomposition of carbon dioxide reveals one distinct pathway in which three cations are formed following excitation of oxygen Is electrons.
    Additional Material: 4 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 7 (1993), S. 555-560 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: The application of fast-atom bombardment mass Spectrometry and collisiorutlly induced dissociation with mass-analysed ion kinetic energy (CID/MIKE) Spectrometry of representative inositol mono-, bis- and trisphos-phates is described. Based on their CID/MIKE spectra, inositol polyphosphates containing vicinal phosphate groups could be distinguished from isomers in which adjacent phosphate groups were absent. The potential value of this procedure in studies of the biochemistry of intracellular second messengers is discussed.
    Additional Material: 3 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Rapid Communications in Mass Spectrometry 8 (1994), S. 217-221 
    ISSN: 0951-4198
    Keywords: Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Physics
    Notes: Nanogram quantities of glucuronic acid conjugates of GR117289 in rat and dog bile have been analysed by semi-microbore high-performance liquid chromatography (HPLC)/ionspray mass spectrometry with on-line UV diode array detection. The determination of drug metabolites in bile has often proved problematical due to the large number of endogenous components in this biological matrix, in particular the bile acids. Semi-microbore HPLC is useful for concentrating small quantities of material and, in combination with an on-line diode array detector, for distinguishing between drug related and endogenous components. A novel angiotensin II receptor antagonist, GR117289, had proved difficult to analyse by thermospray mass spectrometry because of its thermal lability. The use of the less thermally dependent technique of ionspray mass spectrometry allowed the characterization of nanogram quantities of glucuronic acid metabolites of GR117289 in bile.
    Additional Material: 6 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    Chichester [u.a.] : Wiley-Blackwell
    International Journal for Numerical Methods in Engineering 37 (1994), S. 2935-2950 
    ISSN: 0029-5981
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mathematics , Technology
    Notes: The propagation and decay of acoustic waves in exterior domains in an essential ingredient in the study of fluid-structure interaction. A strategy must be devised to compute solutions over domains which are unbounded. Exact impedance conditions at an artificial external boundary are specified by the DtN method, yielding an equivalent problem that is suitable for domain-based computation. The DtN boundary condition is non-reflective, giving rise to exact (and thereby unique) solutions. The truncated DtN operator, which is employed in practice, fails to inhibit the reflection of higher modes, so that non-unique solutions may occur at their harmonics. Simple expressions determine a sufficient number of terms in the truncated operator for unique solutions at any given wave number. There are three characteristic length scales in the computational problem: the radius of the artificial boundary, the geometry of the body (represented by the internal boundary) and the mesh size. Numerical studies examine the dependence of the conditioning of finite element coefficient matrices on the number of terms in the truncated DtN operator vs. the wave number non-dimensionalized by each of the length scales. Analytic results regarding the number of terms sufficient for unique solutions are confirmed. As long as this criterion is respected, no upper limit on the allowable wave number is detected. A local approximation of the boundary conditions restores uniqueness for all wave numbers.
    Additional Material: 9 Ill.
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  • 8
    ISSN: 0749-1581
    Keywords: Zearalenone ; Zearalanone ; 1H and 13C NMR ; Molecular modelling ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The complete 1H and 13C NMR spectra of the mycotoxin zearalenone are described. An analysis of all the vicinal proton-proton coupling constants, together with molecular modelling results, leads to a three-dimensional structure very similar to those observed x-ray crystallographically for related systems. Analogous data on zearalanone reveal that whereas the overall molecular geometry is similar to that of zearalenone, the alkyl terminus of the 12-membered bridging moiety is now oriented almost orthogonally to the aromatic ring plane.
    Additional Material: 10 Ill.
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  • 9
    ISSN: 0749-1581
    Keywords: 1H NMR ; 19F Corticosteroids ; 1H-19F long-range coupling ; Heteronuclear COSY ; 1H-19F 2D correlation ; Chemistry ; Analytical Chemistry and Spectroscopy
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: The analysis of the 1H and 19F NMR spectra of the corticosteroid fluocinonide and five related steroids is reported. The 500 MHz 1H NMR spectra revealed several previously undetected long-range 1H-19F coupling constants. These couplings were assigned by the application of the heteronuclear equivalent of the COSY pulse sequence. The fluorine substituent effects and long-range heteronuclear couplings were examined in relation to structures derived from molecular mechanics (MMX) calculations.
    Additional Material: 6 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    International Journal for Numerical and Analytical Methods in Geomechanics 17 (1993), S. 659-667 
    ISSN: 0363-9061
    Keywords: Engineering ; Engineering General
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Architecture, Civil Engineering, Surveying , Geosciences
    Notes: We present solutions for the effective stress induced by gas flow through a porous solid into a borehole resulting from sudden pressure reduction. Tensile effective stress that exceeds the strength of the solid will lead to borehole failure. This has applications to the intentional creation of cavities, relevant to the efficient recovery of coalbed methane, and the avoidance of borehole stability problems in conventional gas production.
    Additional Material: 3 Ill.
    Type of Medium: Electronic Resource
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