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  • LUNAR AND PLANETARY EXPLORATION  (9)
  • SOLID-STATE PHYSICS  (2)
  • 4-N,N-dimethylaminobenzoic acid  (1)
  • Cell & Developmental Biology
  • 1990-1994  (11)
  • 1980-1984  (1)
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Years
Year
  • 1
    Electronic Resource
    Electronic Resource
    Springer
    Journal of fluorescence 2 (1992), S. 107-115 
    ISSN: 1573-4994
    Keywords: Fluorescence ; anomalous fluorescence ; 4-N,N-dimethylaminobenzoic acid ; dimerization
    Source: Springer Online Journal Archives 1860-2000
    Topics: Physics
    Notes: Abstract 4-N,N-Dimethylaminobenzoic acid exhibits anomalous fluorescence in polar and hydrogen-bonding solvents. The fluorescence spectra and kinetics suggest that this arises due to the formation of a ground-state dimer or higher polymer. Preliminary measurements in hexane containing small amounts of polar acetonitrile do not rule out the possibility of exciplex formation also occurring.
    Type of Medium: Electronic Resource
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  • 2
    Publication Date: 2011-08-24
    Description: Laboratory spectra of the first overtone band (2.1480 microns, 4655.4 reciprocal cm) of solid nitrogen show additional structure at 2.1618 microns (4625.8 reciprocal cm) over a limited temperature range. The spectrum of Neptune's satellite Triton shows the nitrogen overtone band as well as the temperature-sensitive component. The temperature dependence of this band may be used in conjunction with ground-based observations of Triton as an independent means of determining the temperature of surface deposits of nitrogen ice. The surface temperature of Triton is found to be 38.0 +2.0 or -1.0 K, in agreement with previous temperature estimates and measurements. There is no spectral evidence for the presence of alpha-nitrogen on Triton's surface, indicating that there is less than 10 percent carbon monoxide in solid solution with the nitrogen on the surface.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science (ISSN 0036-8075); 261; 5122; p. 751-754.
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  • 3
    Publication Date: 2011-08-24
    Description: Observations of the 1.4- to 2.4-micrometer spectrum of Pluto reveal absorptions of carbon monoxide and nitrogen ices and confirm the presence of solid methane. Frozen nitrogen is more abundant than the other two ices by a factor of about 50; gaseous nitrogen must therefore be the major atmospheric constituent. The absence of carbon dioxide absorptions is one of several differences between the spectra of Pluto and Triton in this region. Both worlds carry information about the composition of the solar nebula and the processes by which icy planetesimals formed.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science (ISSN 0036-8075); 261; 5122; p. 745-748.
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  • 4
    Publication Date: 2011-08-24
    Description: The near-infrared spectrum of Triton reveals ices of nitrogen, methane, carbon monoxide, and carbon dioxide, of which nitrogen is the dominant component. Carbon dioxide ice may be spatially segregated from the other more volatile ices, covering about 10 percent of Triton's surface. The absence of ices of other hydrocarbons and nitriles challenges existing models of methane and nitrogen photochemistry on Triton.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science (ISSN 0036-8075); 261; 5122; p. 742-745.
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  • 5
    Publication Date: 2011-08-24
    Description: Recently Brown et al. (1991) showed that Triton's internal heat source could amount to 5-20% of the absorbed insolation on Triton, thus significantly affecting volatile transport and atmospheric pressure. Subsequently, Kirk and Brown (1991a) used simple analytical models of the effect of internal heat on the distribution of volatiles on Triton's surface, confirming the speculation of Brown et al. that Triton's internal heat flow could strongly couple to the surface volatile distribution. To further explore this idea, we present numerical models of the permanent distribution of nitrogen ice on Triton that include the effects of sunlight, the two-dimensional distribution of internal heat flow, the coupling of internal heat flow to the surface distribution of nitrogen ice, and the finite viscosity of nitrogen ice. From these models we conclude that: (1) The strong vertical thermal gradient induced in Triton's polar caps by internal heat-flow facilitates viscous spreading to lower latitudes, thus opposing the poleward transport of volatiles by sunlight, and, for plausible viscosities and nitrogen inventories, producing permanent caps of considerable latitudinal extent; (2) It is probable that there is a strong coupling between the surface distribution of nitrogen ice on Triton and internal heat flow; (3) Asymmetries in the spatial distribution of Triton's heat flow, possibly driven by large-scale, volcanic activity or convection in Triton's interior, can result in permanent polar caps of unequal latitudinal extent, including the case of only one permanent polar cap; (4) Melting at the base of a permanent polar cap on Triton caused by internal heat flow can significantly enhance viscous spreading, and, as an alternative to the solid-state greenhouse mechanism proposed by Brown et al. (1990), could provide the necessary energy, fluids, and/or gases to drive Triton's geyser-like plumes; (5) The atmospheric collapse predicted to occur on Triton in the next 20 years (Spencer, 1990) may be plausibly avoided because of the large latitudinal extent expected for permanent polar caps on Triton.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Journal of Geophysical Research (ISSN 0148-0227); 99; E1; p. 1695-1981
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  • 6
    Publication Date: 2011-08-19
    Description: The location of active geyser-like eruptions and related features close to the current subsolar latitude on Triton suggests a solar energy source for these phenomena. Solid-state greenhouse calculations have shown that sunlight can generate substantially elevated subsurface temperatures. A variety of models for the storage of solar energy in a subgreenhouse layer and for the supply of gas and energy to a geyser are examined. 'Leaky greenhouse' models with only vertical gas transport are inconsistent with the observed upper limit on geyser radius of about 1.5 km. However, lateral transport of energy by gas flow in a porous N2 layer with a block size on the order of a meter can supply the required amount of gas to a source region about 1 km in radius. The decline of gas output to steady state may occur over a period comparable with the inferred active geyser lifetime of 5 earth years. The required subsurface permeability may be maintained by thermal fracturing of the residual N2 polar cap. A lower limit on geyser source radius of about 50 to 100 m predicted by a theory of negatively buoyant jets is not readily attained.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: Science (ISSN 0036-8075); 250; 424-429
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  • 7
    Publication Date: 2011-08-19
    Description: A singular perturbation analysis valid for small grain-boundary slopes is used with the one-sided model for solidification to show that grain boundaries introduce imperfections into the symmetry of the developing cellular interfaces which rupture the junction between the family of planar shapes and the bifurcating cellular families. Undulating interfaces are shown to develop first near grain boundaries, and to evolve with decreasing temperature gradient either by a smooth transition from the almost planar family or by a sudden jump to moderate-amplitude cellular forms, depending on the growth rate.
    Keywords: SOLID-STATE PHYSICS
    Type: Physical Review B, 3rd Series (ISSN 0163-1829); 30; 3993-399
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  • 8
    Publication Date: 2011-08-24
    Description: Data regarding the Uranian satellites' radii, masses, mean density, and, consequently, their internal structures obtained from the Voyager encounter are analyzed. Topics covered are the sizes, shapes, topography, masses, densities, and models of the internal structures of the five major satellites. The sizes and shapes of the 10 small satellites discovered by Voyager 2 are discussed. The physical properties of the large satellites of Uranus are compared to those other satellites in the outer solar system, particularly those of Jupiter and Saturn, and the implications that these comparisons have for understanding the origin and evolution of the satellites of Uranus are discussed.
    Keywords: LUNAR AND PLANETARY EXPLORATION
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  • 9
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    In:  Other Sources
    Publication Date: 2019-01-25
    Description: The solid state greenhouse models were constrained for water ice surfaces using thermal eclipse data. As a result, it was determined that at depths of 3 cm or more Europa can have about a 30 K temperature enhancement over the diurnal mean surface temperature of about 97 K at the equator. It was also determined that the unusual shape of Europa's thermal flux curves during eclipses can be explained by the solid state greenhouse effect. The solid state greenhouse models were applied to the problem of the origin and energy sources of Triton's geyser-like plumes. Two classes of models are examined which may explain the driving energy for Triton's plumes. Triton's internal heatflow is recognized as a major contributor to its global energy balance. Internal heat flow from radioactive decay in Triton's interior along with absorbed thermal energy from Neptune total 5 to 20 pct. of the insolation absorbed by Triton, thus comprising a significant fraction of Triton's surface energy balance.
    Keywords: LUNAR AND PLANETARY EXPLORATION
    Type: NASA, Washington, Reports of Planetary Geology and Geophysics Program, 1990; p 15-16
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  • 10
    Publication Date: 2019-08-28
    Description: The wide range of length and time scales involved in industrial scale solidification processes is demonstrated here by considering the Czochralski process for the growth of large diameter silicon crystals that become the substrate material for modern microelectronic devices. The scales range in time from microseconds to thousands of seconds and in space from microns to meters. The physics and chemistry needed to model processes on these different length scales are reviewed.
    Keywords: SOLID-STATE PHYSICS
    Type: In: Heat and mass transfer in materials processing (A93-10826 01-31); p. 137-153.
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