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  • Articles  (37)
  • Polymer and Materials Science  (20)
  • Life and Medical Sciences  (13)
  • Physical Chemistry  (4)
  • 1990-1994  (25)
  • 1980-1984  (11)
  • 1950-1954  (1)
  • 1940-1944
  • 1
    ISSN: 0006-3525
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology
    Notes: C-terminal analogues of neuropeptide Y (NPY) of small molecular size have been synthesized. The influence of chain length, single or multiple amino acid substitution, and segment substitutions on receptor binding, pre- and postsynaptic biological activity, and conformational properties have been investigated. Receptor binding and in vivo assays revealed biological activity for NPY Ac-25-36 that increased with increasing α-helicity. In attempts to stabilize the α-helical content, three independent types of modified NPY Ac-25-36 analogues were synthesized. Strong agonistic activities could be detected in a series of discontinuous analogues, which are constructs of N-terminal parts linked via different spacer molecules to C-terminal segments. One of the most active molecules was NPY 1-4-Aca-25-36 (Aca, ε-aminocaproic acid). For the first time conformational properties of a series of small NPY analogues have been investigated by CD, and correlated with biological activity and receptor binding. A C-terminal dodecapeptide segment of NPY with an amount of 50% substitution to the native C-terminal sequence of NPY was found to exhibit significant receptor binding.
    Additional Material: 6 Ill.
    Type of Medium: Electronic Resource
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  • 2
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 54 (1982), S. 530-531 
    ISSN: 0009-286X
    Keywords: Elektrochemie ; Festbett-Elektroden ; Graphit ; Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Additional Material: 2 Ill.
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  • 3
    Electronic Resource
    Electronic Resource
    Weinheim : Wiley-Blackwell
    Chemie Ingenieur Technik - CIT 54 (1982), S. 809-817 
    ISSN: 0009-286X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Process Engineering, Biotechnology, Nutrition Technology
    Notes: New battery systems. The reversible storage of electrical energy plays a central role in the development of electric vehicles, load levelling in power stations, and technical utilization of solar energy. Electrochemistry offers interesting solutions with optimal energy density; however, these have reached technical maturity in only a few cases. The conventional lead/acid accumulator is being further improved among aqueous systems. Moreover, various other lines of development have been initiated in recent years, such as nickel/zinc and chlorine/zinc accumulators, which offer totally fresh perspectives from an electrochemical and engineering point of view. In the case of zinc/air and aluminium/air batteries, external redeposition of the metal is envisaged. From a practical point of view, aqueous systems are unsurpassable. Metals with an extremely high negative potential like sodium or lithium can only be cycled in the absence of water. Systems with molten salts or solid electrolytes do not suffer from this drawback. The sodium/sulfur battery, which is characterized by readily available cell components of low environmental impact, is presently undergoing intensive development. However, thermal discharge represents a technical problem. The future of these new developments will be governed by their economics, energy density, energy efficiency, power density, and last but not least by their cyclability. These properties have not yet been optimized in a single system.
    Additional Material: 15 Ill.
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  • 4
    Electronic Resource
    Electronic Resource
    New York : Wiley-Blackwell
    Die Makromolekulare Chemie 194 (1993), S. 2725-2739 
    ISSN: 0025-116X
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Physics
    Notes: The galvanostatic electropolymerization of thiophene (1), 3-methylthiophene (2) and 2,2′-bithiophene (3) in acetonitrile, containing 0,002 to 20 mol/L water, was studied in detail. The current efficiency γ for the polymer film formation decreased rapidly for 1, but much slower for 2 and 3 with increasing water concentration cH2O. For cH2O = 0,1 mol/L, γ was found to be 10, 82 and 95% for 1-3. It was possible to describe the experimental γ vs. cH2O plots quantitatively by a model where the electrogenerated radical cations (rc) of the thiophene (derivative) are consumed by two competing second-order follow up reactions, the nucleophilic attack of the rc by water (i) and the rate-determining dimerization of two rc's (ii). Their rates are given by: (i) v1 = k1 crc cH2O and (ii) v2 = k2 c2rc. The side reaction (i) leads to soluble products, while reaction (ii) contributes to the polymer film growth. The ratio k1/k2 was found to be 3 · 10-7, 2 · 10-8 and 4 · 10-9 for 1, 2 and 3, respectively, and this shows that the electropolymerization of 2,2′-bithiophene is by a factor of about 100 less sensitive toward the present water than thiophene. The steady state concentration crc is in the order of 10-9 mol/L in all three cases. The relative insensitivity of doping/undoping cycles with respect to the presence of water is discussed in terms of a lessened reactivity of the polarons and a low solubility of water in the heteroaromatic polymer.
    Additional Material: 10 Ill.
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  • 5
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Morphology 180 (1984), S. 105-124 
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The anatomy of neurons of the stomatogastric nervous system of Ascheta domesticus was studied using heavy metal iontophoresis through cut nerve ends followed by silver intensification. Nineteen categories of neuron are described and compared with neurons known from the stomatogastric nervous system of other insects. Possible functions for the neurons are suggested. Motor neuron candidates are suggested for all parts of the gut served by the stomatogastric nervous system, and axons of sensory neurons of the anterior pharynx are located. There are four neuron types that cannot readily be assigned motor, sensory, or interneuron functions: large dorsal cells of the frontal ganglion; the two neurons of the nervus connectivus, and two categories of neurons in the median neurosecretory cell group of the pars intercerebralis, the axons of which are contained in the stomatogastric nerves.
    Additional Material: 18 Ill.
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  • 6
    Electronic Resource
    Electronic Resource
    New York, NY : Wiley-Blackwell
    Journal of Morphology 180 (1984), S. 81-103 
    ISSN: 0362-2525
    Keywords: Life and Medical Sciences ; Cell & Developmental Biology
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Biology , Medicine
    Notes: The distribution of the ganglia and nerves of the stomatogastric nervous system and the innervation of the extrinsic and intrinsic muscles are described. Median unpaired frontal and hypocerebral ganglia and paired ingluvial ganglia are present. The anterior pharynx is innervated by branches of the frontal nerve and by the anterior and posterior pharyngeal nerves, originating from the frontal ganglion. The posterior pharyngeal nerves are linked to nerves innervating the posterior part of the pharynx which have their origin in the hypocerebral ganglion, the anterior portion of which has previously been regarded as part of the recurrent nerve. Paired esophageal nerves run the length of the esophagus and crop between the hypocerebral and and ingluvial ganglia, innervating the muscularis by serial side branches. From each ingluvial ganglion runs an ingluvial nerve which innervates the gizzard and a cecal nerve which innervates the midgut and its ceca. At the posterior end of the midgut there is a poorly developed nerve ring. Nerves running posteriorly from this nerve ring link the stomatogastric nervous system with the proctodeal innervation from the terminal abdominal ganglion.Multipolar peripheral neurons are present on the muscularis of the whole of the foregut, rather randomly distributed on the crop and gizzard but forming fairly definite groupings at some points on the pharynx. Though of varied appearance, these cells could not be divided into discrete morphological categories. Peripheral neurons on the midgut are of different and characteristic morphology, though a few cells of the same appearance as those of the foregut occur at the midgut-hindgut boundary. Nerve fibers on the gut almost invariably terminate on the fibers of the muscularis.
    Additional Material: 12 Ill.
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  • 7
    Electronic Resource
    Electronic Resource
    New York, NY [u.a.] : Wiley-Blackwell
    Journal of Applied Polymer Science 29 (1984), S. 3569-3577 
    ISSN: 0021-8995
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Notes: A model N-methylol reactant system based on pyrrolidone derivatives has been used to study the chemical factors that control formaldehyde release. Fabric samples of known composition were prepared from chemically pure reactants and formaldehyde release was determined by the AATCC Sealed Jar Test. This work provides support for prior suggestions and a more direct approach for understanding unexpected results from tests on post-and precure fabrics. In addition, new findings demonstrate that the N-methylol reactant, its byproducts, and pure zinc nitrate are capable of reducing the level of formaldehyde release.
    Additional Material: 6 Tab.
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  • 8
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
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  • 9
    ISSN: 0935-9648
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Chemistry and Pharmacology , Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics , Physics
    Additional Material: 3 Ill.
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  • 10
    Electronic Resource
    Electronic Resource
    Weinheim [u.a.] : Wiley-Blackwell
    Materials and Corrosion/Werkstoffe und Korrosion 5 (1954), S. 118-118 
    ISSN: 0947-5117
    Keywords: Chemistry ; Polymer and Materials Science
    Source: Wiley InterScience Backfile Collection 1832-2000
    Topics: Mechanical Engineering, Materials Science, Production Engineering, Mining and Metallurgy, Traffic Engineering, Precision Mechanics
    Type of Medium: Electronic Resource
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